2,4,6-Triphenylphenol

Base Information

• Chemical Name: 2,4,6-Triphenylphenol
• CAS No.: 3140-01-0
• Molecular Formula: C24H18 O
• Molecular Weight: 322.406
• Hs Code.: 2906299090
• European Community (EC) Number: 621-894-4
• DSSTox Substance ID: DTXSID00185321
• Nikkaji Number: J1.689.735C
• Wikidata: Q83056346
• Mol file: 3140-01-0.mol

Synonyms:2,4,6-triphenylphenol;3140-01-0;5'-Phenyl-(1,1':3',1''-terphenyl)-2'-ol;(1,1':3',1''-Terphenyl)-2'-ol, 5'-phenyl-;SCHEMBL309670;C24H18O;DTXSID00185321;AKOS024342539;PD147966;5'-Phenyl[1,1':3',1''-terphenyl]-2'-ol;5'-Phenyl[1,1';3',1''-terphenyl]-2'-ol;3',1'']-terphenyl-2'-ol

Chemical Property of 2,4,6-Triphenylphenol

Chemical Property:

• Vapor Pressure: 3.91E-09mmHg at 25°C
• Boiling Point: 461.4°Cat760mmHg
• Flash Point: 216.7°C
• PSA: 20.23000
• Density: 1.136g/cm³
• LogP: 6.39320
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 322.135765193
• Heavy Atom Count: 25
• Complexity: 359

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC(=C(C(=C2)C3=CC=CC=C3)O)C4=CC=CC=C4

Technology Process of 2,4,6-Triphenylphenol

There total 17 articles about 2,4,6-Triphenylphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2,4,6-tribromophenol (118-79-6) + phenylboronic acid (98-80-6) → 2,4,6-triphenylphenol (3140-01-0)

Guidance literature:

With sodium carbonate; palladium diacetate; In water; N,N-dimethyl-formamide; at 60 ℃; for 12h;

DOI:10.1021/jo060122v

Reference yield: 86.0%

2,4,6-triphenylanisole (115292-92-7) → 2,4,6-triphenylphenol (3140-01-0)

Guidance literature:

With boron tribromide; In dichloromethane; at 0 ℃; for 3h; Inert atmosphere;

DOI:10.1016/j.tetlet.2017.05.040

Reference yield: 82.0%

sodium (phenyltrihydroxyborate) + 2,4,6-tribromophenol (118-79-6) → 2,4,6-triphenylphenol (3140-01-0)

Guidance literature:

With tetrabutylammomium bromide; palladium diacetate; In water; at 20 ℃; for 24h;

DOI:10.1039/c0gc00122h

upstream raw materials:

2,4,6-triphenylaniline

nitromethane

2,4,6-triphenylpyrylium tetrafluoroborate

2,4,6-triphenyl-4-(2,4,6-triphenyl-phenoxy)-cyclohexa-2,5-dienone

Downstream raw materials:

2,4,6-triphenylphenoxyl radical

Ta(OC₆H₂(C₆H₅)3)2Cl₃

2,4,6-triphenylphenoxyl

2,4,6-triphenyl-4-(2,4,6-triphenyl-phenoxy)-cyclohexa-2,5-dienone

Refernces

• 1、 Hayashi, Naoto,Ueno, Taisetsu,Okamoto, Naoki,Mori, Takahiro,Sasaki, Naho,Kamoto, Taku,Yoshino, Junro,Higuchi, Hiroyuki,Uekusa, Hidehiro,Tukada, Hideyuki. "Binary amorphous solids consisting of 2,4,6-triarylphenoxyl radicals and their dimers". . p. 2547 - 2550. Retrieved 2017/06/13.
• 2、 Basu, Basudeb,Biswas, Kinkar,Kundu, Sekhar,Ghosh, Sujit. "Highly effective alternative aryl trihydroxyborate salts for a ligand-free, on-water Suzuki-Miyaura coupling reaction". experimental part. p. 1734 - 1738. Retrieved 2011/02/22.