2,4,6-Triphenylphenoxyl

Base Information

• Chemical Name: 2,4,6-Triphenylphenoxyl
• CAS No.: 10384-15-3
• Molecular Formula: C₄₈H₃₄O₂
• Molecular Weight: 642.797
• Mol file: 10384-15-3.mol

Synonyms:2,5-Cyclohexadien-1-one,2,4,6-triphenyl-4-(2,4,6-triphenylphenoxy)- (7CI); 2,5-Cyclohexadien-1-one,2,4,6-triphenyl-4-[(5'-phenyl-m-terphenyl-2'-yl)oxy]- (8CI)

Chemical Property of 2,4,6-Triphenylphenoxyl

Chemical Property:

• PSA: 26.30000
• LogP: 11.71180

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4,6-Triphenylphenoxyl

There total 12 articles about 2,4,6-Triphenylphenoxyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4,6-tribromoanisole (607-99-8) → 2,4,6-triphenylphenoxyl (4647-83-0) + 2,4,6-triphenyl-4-(2,4,6-triphenyl-phenoxy)-cyclohexa-2,5-dienone (10384-15-3)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / toluene; water / 8 h / Inert atmosphere; Reflux

2: boron tribromide / dichloromethane / 3 h / 0 °C / Inert atmosphere

3: potassium hexacyanoferrate(III); sodium hydroxide / water; benzene

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; boron tribromide; sodium carbonate; sodium hydroxide; potassium hexacyanoferrate(III); In dichloromethane; water; toluene; benzene;

DOI:10.1016/j.tetlet.2017.05.040

Reference yield:

phenylboronic acid (98-80-6) → 2,4,6-triphenylphenoxyl (4647-83-0) + 2,4,6-triphenyl-4-(2,4,6-triphenyl-phenoxy)-cyclohexa-2,5-dienone (10384-15-3)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / toluene; water / 8 h / Inert atmosphere; Reflux

2: boron tribromide / dichloromethane / 3 h / 0 °C / Inert atmosphere

3: potassium hexacyanoferrate(III); sodium hydroxide / water; benzene

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; boron tribromide; sodium carbonate; sodium hydroxide; potassium hexacyanoferrate(III); In dichloromethane; water; toluene; benzene;

DOI:10.1016/j.tetlet.2017.05.040

Reference yield:

2,4,6-triphenylanisole (115292-92-7) → 2,4,6-triphenylphenoxyl (4647-83-0) + 2,4,6-triphenyl-4-(2,4,6-triphenyl-phenoxy)-cyclohexa-2,5-dienone (10384-15-3)

Guidance literature:

Multi-step reaction with 2 steps

1: boron tribromide / dichloromethane / 3 h / 0 °C / Inert atmosphere

2: potassium hexacyanoferrate(III); sodium hydroxide / water; benzene

With boron tribromide; sodium hydroxide; potassium hexacyanoferrate(III); In dichloromethane; water; benzene;

DOI:10.1016/j.tetlet.2017.05.040

upstream raw materials:

tetrachloromethane

2,4,6-triphenylphenoxyl radical

chloroform

2,4,6-triphenylphenol

Downstream raw materials:

2,4,6-tri-tert-butyl-4-(2,4,6-triphenyl-phenoxy)-cyclohexa-2,5-dienone

(2,4,6-triphenyl-phenyl)-trityl ether

4-Ethoxy-2,4,6-triphenyl-cyclohexadien-(2,5)-on

2-Methoxy-2,4,6-triphenyl-cyclohexadien-(3,5)-on