1,3,2-Dioxaborinane, 2-(3-phenylpropyl)-

Base Information

• Chemical Name: 1,3,2-Dioxaborinane, 2-(3-phenylpropyl)-
• CAS No.: 132350-29-9
• Molecular Formula: C12H17BO2
• Molecular Weight: 204.077
• Mol file: 132350-29-9.mol

Synonyms:

Chemical Property of 1,3,2-Dioxaborinane, 2-(3-phenylpropyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,2-Dioxaborinane, 2-(3-phenylpropyl)-

There total 5 articles about 1,3,2-Dioxaborinane, 2-(3-phenylpropyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2-(3-phenyl-2-propenyl)-1,3,2-dioxaborinane → 2-(3-phenylpropyl)-1,3,2-dioxaborinane (132350-29-9)

Guidance literature:

With hydrogen; In tetrahydrofuran; under N2; addn. of catalytic amount of 5% Pd on carbon to soln. of B-compd., hydrogenated at 25°C and 1 atm pressure over a period of 6-8 h; filtered under N2, evapd.;

Reference yield:

C7H8O3S*C9H11I → 2-(3-phenylpropyl)-1,3,2-dioxaborinane (132350-29-9)

Guidance literature:

Multi-step reaction with 3 steps

1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium phosphate monohydrate; di-tert-butyl(methyl)phosphonium tetrafluoroborate salt / water; tert-butyl alcohol / 60 °C / Inert atmosphere

2: hydrogenchloride; sodium periodate / tetrahydrofuran; water / 3 h / 20 °C

3: benzene / 12 h / Reflux

With hydrogenchloride; sodium periodate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium phosphate monohydrate; di-tert-butyl(methyl)phosphonium tetrafluoroborate salt; In tetrahydrofuran; water; tert-butyl alcohol; benzene;

DOI:10.1021/jo301156e

Reference yield:

1-iodo-3-phenylpropan (4119-41-9) → 2-(3-phenylpropyl)-1,3,2-dioxaborinane (132350-29-9)

Guidance literature:

Multi-step reaction with 3 steps

1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium phosphate monohydrate; di-tert-butyl(methyl)phosphonium tetrafluoroborate salt / water; tert-butyl alcohol / 60 °C / Inert atmosphere

2: hydrogenchloride; sodium periodate / tetrahydrofuran; water / 3 h / 20 °C

3: benzene / 12 h / Reflux

With hydrogenchloride; sodium periodate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium phosphate monohydrate; di-tert-butyl(methyl)phosphonium tetrafluoroborate salt; In tetrahydrofuran; water; tert-butyl alcohol; benzene;

DOI:10.1021/jo301156e

upstream raw materials:

1-iodo-3-phenylpropan

1-Bromo-3-phenylpropane

(3-phenylpropyl)boronic acid

trimethyleneglycol