(η5-pentamethylcyclopentadienyl){(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I)

Base Information

Chemical Name:(η5-pentamethylcyclopentadienyl){(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I)
CAS No.:110354-18-2
Molecular Formula:C₄₇H₄₅CuP₂
Molecular Weight:735.368
Hs Code.:

Synonyms:

Suppliers and Price of (η5-pentamethylcyclopentadienyl){(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η5-pentamethylcyclopentadienyl){(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I)

Chemical Property:

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Technology Process of (η5-pentamethylcyclopentadienyl){(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I)

There total 3 articles about (η5-pentamethylcyclopentadienyl){(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 86847-08-7
{(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I) chloride

: 94348-92-2
potassium pentamethylcyclopentadiene

: 110354-18-2
(η5-pentamethylcyclopentadienyl){(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I)

Guidance literature:: In tetrahydrofuran; KC5Me5 was added portionwise to a THF soln. of Cu-complex under Ar, mixt. was stirred at 0°C for 2 h; carefully filtered through a layer of Na2SO3 (water cooling), concd., covered with a layer of pentane and stored at -15°C; elem. anal.;

Reference yield:

: 103559-83-7
hexaphenylcarbodiphosphorane

: 110354-18-2
(η5-pentamethylcyclopentadienyl){(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I)

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: tetrahydrofuran

In tetrahydrofuran;

Reference yield:

: 51905-34-1
pentamethylcyclopentadienyllithium

: 103559-83-7
hexaphenylcarbodiphosphorane

: copper(l) chloride

: 110354-18-2
(η5-pentamethylcyclopentadienyl){(triphenylphosphonio)(triphenylphosphoranylidene)methyl}copper(I)

Guidance literature:: In tetrahydrofuran; a suspn. of CuCl was mixed with LiC5Me5 at -78°C, the resulting yellow soln. was quenched with a THF soln. of (Ph3P)2C at -78°C; carefully filtered through a layer of Na2SO3 (water cooling), concd., covered with a layer of pentane and stored at -15°C;