Ru(CO₂)(CH₃COO)2(tri(n-butyl)phosphine)[tris(4-fluorophenyl)phosphine]

Base Information

Chemical Name:Ru(CO₂)(CH₃COO)2(tri(n-butyl)phosphine)[tris(4-fluorophenyl)phosphine]
CAS No.:870636-55-8
Molecular Formula:C₃₆H₄₅F₃O₆P₂Ru
Molecular Weight:793.762
Hs Code.:

Ru(CO<sub>2</sub>)(CH<sub>3</sub>COO)2(tri(n-butyl)phosphine)[tris(4-fluorophenyl)phosphine]

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ru(CO₂)(CH₃COO)2(tri(n-butyl)phosphine)[tris(4-fluorophenyl)phosphine]

Chemical Property:

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Technology Process of Ru(CO₂)(CH₃COO)2(tri(n-butyl)phosphine)[tris(4-fluorophenyl)phosphine]

There total 1 articles about Ru(CO₂)(CH₃COO)2(tri(n-butyl)phosphine)[tris(4-fluorophenyl)phosphine] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.5%

: 847223-99-8
Ru(CO)2(κ1-O-CH3COO)(κ2-O,O'-CH3COO)(tri(n-butyl)phosphine)

: 18437-78-0
P(p-C₆H₄F)3

: 870636-55-8
Ru(CO₂)(CH₃COO)2(tri(n-butyl)phosphine)[tris(4-fluorophenyl)phosphine]

: 870636-61-6
Ru(CO₂)(CH₃COO)2[tris(4-fluorophenyl)phosphine]2

Guidance literature:: In n-heptane; acetic acid; ligand added to soln. of Ru-complex in acetic acid and heptane; stirred and heated at 40°C for 6 h; solvents distd. (vac.) at temp. lower 40°C; residue dissolved in CH2Cl2 and heptane added; soln. concd. by bubbling N2 at room temp.; solid filtered, washed (pentane), dried (vac.), purified by several extns. (heptane) under N2 at ...; elem.anal.;
DOI:10.1016/j.jorganchem.2005.07.100

Reference yield:

: 870636-55-8
Ru(CO₂)(CH₃COO)2(tri(n-butyl)phosphine)[tris(4-fluorophenyl)phosphine]

: 1333-74-0
hydrogen

: 847223-99-8
Ru(CO)2(κ1-O-CH3COO)(κ2-O,O'-CH3COO)(tri(n-butyl)phosphine)

: 870636-56-9
RuH₂(CO₂)(tri(n-butyl)phosphine)[tris(4-fluorophenyl)phosphine]

Guidance literature:: With sodium carbonate; In benzene-d6; byproducts: CH3COONa; High Pressure; to Ru-complex, NaCO3 added C6D6 in stainless steel autoclave under N2 atm.; H2 added under 100 bar; autoclave heated at 60°C for 14 h; autoclave cooled rapidly to room temp.; gas vented; mixt. filtered under N2 atm.; not isolated; monitored by NMR and IR spectroscopy;
DOI:10.1016/j.jorganchem.2005.07.100