Mo₂(2,4,6-triisopropyl benzoate)2(5-ethynylthiophene-2-carboxylate)2

Base Information

• Chemical Name: Mo₂(2,4,6-triisopropyl benzoate)2(5-ethynylthiophene-2-carboxylate)2
• CAS No.: 1436861-03-8
• Molecular Formula: C₄₆H₅₂Mo₂O₈S₂
• Molecular Weight: 988.926
• Mol file: 1436861-03-8.mol

Synonyms:

Chemical Property of Mo₂(2,4,6-triisopropyl benzoate)2(5-ethynylthiophene-2-carboxylate)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mo₂(2,4,6-triisopropyl benzoate)2(5-ethynylthiophene-2-carboxylate)2

There total 1 articles about Mo₂(2,4,6-triisopropyl benzoate)2(5-ethynylthiophene-2-carboxylate)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

5-ethynylthiophene-2-carboxylic acid (174672-58-3) + Mo2(2,4,6-triisopropyl benzoate)4 (412296-04-9) → Mo2(2,4,6-triisopropyl benzoate)2(5-ethynylthiophene-2-carboxylate)2 (1436861-03-8)

Guidance literature:

In toluene; at 20 ℃; for 96h; Inert atmosphere;

DOI:10.1021/ja400508u

Reference yield:

iodobenzene (591-50-4) + Mo2(2,4,6-triisopropyl benzoate)2(5-ethynylthiophene-2-carboxylate)2 (1436861-03-8) → Mo2(2,4,6-triisopropyl benzoate)2(ThCCPh)2 (1436861-05-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; for 20h; Inert atmosphere;

DOI:10.1021/ja400508u

Reference yield:

(triphenylphosphine)gold(I) chloride (14243-64-2) + Mo2(2,4,6-triisopropyl benzoate)2(5-ethynylthiophene-2-carboxylate)2 (1436861-03-8) → Mo2(2,4,6-triisopropyl benzoate)2(ThCCAuPPh3)2

Guidance literature:

With triethylamine; In tetrahydrofuran; dichloromethane; for 48h; Inert atmosphere;

DOI:10.1021/ja400508u

upstream raw materials:

5-ethynylthiophene-2-carboxylic acid

Mo₂(2,4,6-triisopropyl benzoate)4

Downstream raw materials:

Mo₂(2,4,6-triisopropyl benzoate)2(ThCCPh)2