C₁₃H₁₆

Base Information

• Chemical Name: C₁₃H₁₆
• CAS No.: 122603-36-5
• Molecular Formula: C₁₃H₁₆
• Molecular Weight: 172.27
• Mol file: 122603-36-5.mol

Synonyms:

Chemical Property of C₁₃H₁₆

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of C₁₃H₁₆

There total 10 articles about C₁₃H₁₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

triethyl borane (97-94-9) + allyl alcohol (107-18-6) + phenylacetylene (536-74-3) → [(E)-2-ethylpenta-1,4-dien-1-yl]benzene (122603-36-5,120814-22-4)

Guidance literature:

With palladium(II) acetylacetonate; triphenylphosphine; In tetrahydrofuran; at 50 ℃; for 72h; stereoselective reaction; Inert atmosphere;

DOI:10.3987/COM-12-S(N)70

Reference yield: 50.0%

1,2-dichloro-ethane (107-06-2,52399-93-6) + 1-phenyl-4-penten-1-yne (4289-20-7) → C13H16 (122603-36-5) + (Z)-penta-1,4-dien-1-ylbenzene (97632-25-2)

Guidance literature:

1,2-dichloro-ethane; 1-phenyl-4-penten-1-yne; With bis(cyclopentadienyl)titanium dichloride; ethylaluminum dichloride; magnesium; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; hexane; water; at 20 ℃; regioselective reaction;

DOI:10.1134/S1070428008060018

Reference yield: 50.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + 1-phenylpropadiene (2327-99-3) → 1-phenylmethylenecyclopropane (7555-67-1) + (E)-(2-ethylbuta-1,3-dien-1-yl)benzene (122603-32-1) + 1-phenyl-2-ethyl-1,4-pentadiene (120814-22-4,122603-36-5) + cis-2-methyl-1-phenyl-1,5-hexadiene (122603-34-3)

Guidance literature:

With palladium diacetate; In diethyl ether; at -10 - -5 ℃; Yield given. Further byproducts given. Title compound not separated from byproducts;

upstream raw materials:

1-phenyl-1-butyne

allyl phenyl ether

triethyl borane

allyl alcohol