122603-34-3Relevant academic research and scientific papers
Triflimide-catalyzed allyl-allyl cross-coupling: A metal-free allylic alkylation
Ding, Feiqing,William, Ronny,Wang, Fei,Liu, Xue-Wei
supporting information; experimental part, p. 8709 - 8711 (2012/10/08)
A highly efficient metal-free intermolecular C(sp3)-C(sp3) allyl-allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.
Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates
Jimenez-Aquino, Agustin,Ferrer Flegeau, Emmanuel,Schneider, Uwe,Kobayashi, Shu
supporting information; experimental part, p. 9456 - 9458 (2011/10/02)
We developed catalytic intermolecular C(sp3)-C(sp3) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be crucial in terms of reactivity.
Palladium(0) versus nickel(0) catalysis in selective functional- grouptolerant sp3-sp3 carbon-carbon bond formations
Flegeau, Emmanuel Ferrer,Schneider, Uwe,Kobayashi, Shue
experimental part, p. 12247 - 12254 (2010/06/11)
We have uncovered Pd°-catalyzed intermolecular nonsymmetrical Suzuki-Miyaura-type sp3-sp3 C-C bond formations between allyl carbonates and nontoxic allyl, allenyl, or propargyl boronates. This report represents the first use of these
OLIGOMETHYLENATION OF PHENYLALLENE WITH DIAZOMETHANE IN THE PRESENCE OF PALLADIUM DIACETATE
Lukin, K. A.,Zefirov, N. S.
, p. 82 - 86 (2007/10/02)
In the reaction of phenylallene with diazomethane in the presence of palladium(II) acetate oligomethylenation takes place in addition to cyclopropanation.It leads to the inclusion of three and four equivalences of methylene in the allene molecule.
