[Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-N3)(N3)]2

Base Information

Chemical Name:[Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-N3)(N3)]2
CAS No.:1234359-86-4
Molecular Formula:C₂₂H₂₄Cu₂N₂₀S₂
Molecular Weight:759.791
Hs Code.:

Synonyms:

Suppliers and Price of [Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-N3)(N3)]2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-N3)(N3)]2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-N3)(N3)]2

There total 2 articles about [Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-N3)(N3)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: sodium azide

: copper(II) perchlorate hexahydrate

: 887114-97-8
1-methyl-2-[o-(methylsulfanyl)phenylazo]imidazole

: 1234359-86-4
[Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-N3)(N3)]2

Guidance literature:: In methanol; N2; MeOH soln. of ligand added dropwise at 298 K to meOH soln. of Cu(ClO4)*6H2O (1:1 molar ratio), stirred for 10 min, MeOH soln. of NaN3 (2.5 equiv.) added; filtered, crystd. on storage for 1 wk, filtered off, washed (water, MeOH), dried (vac.), elem. anal.;
DOI:10.1002/ejic.200900648

Reference yield: 58.0%

: sodium azide

: [Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-MeOH)(N3)]2

: 1234359-86-4
[Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-N3)(N3)]2

Guidance literature:: With Cl₂; In methanol; water; N2; MeOH satd. with Cl2 added to MeOH suspn. of Cu compd. with stirring,stirred for 45 min, N2 bubbled with stirring, excess NaN3 in H2O added, air bubbled with stirring; filtered, crystd. on cooling, filtered off, washed (H2O, MeOH), recrystd. (2-methoxy ethanol/MeOH=1/5), elem. anal.;
DOI:10.1002/ejic.200900648

Reference yield: 42.0%

: 67-56-1
methanol

: sodium azide

: 1234359-86-4
[Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-N3)(N3)]2

: [Cu(1-methyl-2-[o-(thiomethyl)phenylazo]imidazole)(μ-MeOH)(N3)]2

Guidance literature:: With ascorbic acid; In methanol; water; N2; aq. soln. of ascorbic acid (0.5 mmol) added to MeOH suspn. of Cu compd. (0.26 mmol) with stirring, stirred for 30 min, excess NaN3 added, stirred; filtered off, washed (H2O, MeOH), dried over CaCl2, recrystd. (CH2Cl2/hexane), elem. anal.;
DOI:10.1002/ejic.200900648