Fe₂Pt(CO)9(P(C₆H₅)3)

Base Information

• Chemical Name: Fe₂Pt(CO)9(P(C₆H₅)3)
• CAS No.: 34852-99-8
• Molecular Formula: C₂₇H₁₅Fe₂O₉PPt
• Molecular Weight: 821.158
• Mol file: 34852-99-8.mol

Synonyms:

Chemical Property of Fe₂Pt(CO)9(P(C₆H₅)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe₂Pt(CO)9(P(C₆H₅)3)

There total 3 articles about Fe₂Pt(CO)9(P(C₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

disodium octacarbonyldiferrate + cis-triphenylphosphinecarbonylplatinum(II) dichloride (22585-09-7,73347-20-3,19618-78-1) → Fe2Pt(CO)9(P(C6H5)3) (34852-99-8)

Guidance literature:

With NaCl; In tetrahydrofuran; inert atmosphere; mixing at -60°C, slow warming to 20°C (during 2 h); not isolated, determined by NMR spectroscopy;

Reference yield:

tetracarbonylferrate(2-) + trans-bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) → tricarbonyl bis(triphenylphosphine) iron (14741-34-5,21255-52-7) + tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) + Fe2Pt(CO)9(P(C6H5)3) (34852-99-8)

Guidance literature:

With PPh₃; In not given; inert atmosphere; mixing at -76°C, warming to 25°C; chromy.;

Reference yield:

diiron nonacarbonyl (15321-51-4) + [Pt5(CO)(μ-CO)5(PPh3)4] → tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) + Fe2Pt(CO)9(P(C6H5)3) (34852-99-8) + FePt5(CO)9(P(C6H5)3)4

Guidance literature:

In tetrahydrofuran; inert atmosphere; stirring (2 h); not isolated, determined by NMR spectroscopy;

upstream raw materials:

trans-bis(benzonitrile)dichloroplatinum(II)

cis-triphenylphosphinecarbonylplatinum(II) dichloride

diiron nonacarbonyl

Downstream raw materials:

tricarbonyl bis(triphenylphosphine) iron

tetracarbonyl(triphenylphosphine)iron

Fe₂Pt(CO)8(P(C₆H₅)3)2

{(CO)4FeFe(CO)4Pt(P(C₆H₅)3)(P(OC₂H₅)3)}