trans-[Ni(2,6-dimethoxyphenyl)2(PMe₃)2]

Base Information

Chemical Name:trans-[Ni(2,6-dimethoxyphenyl)2(PMe₃)2]
CAS No.:79973-29-8
Molecular Formula:C₂₂H₃₆NiO₄P₂
Molecular Weight:485.163
Hs Code.:

trans-[Ni(2,6-dimethoxyphenyl)2(PMe<sub>3</sub>)2]

Synonyms:

Suppliers and Price of trans-[Ni(2,6-dimethoxyphenyl)2(PMe₃)2]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-[Ni(2,6-dimethoxyphenyl)2(PMe₃)2]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-[Ni(2,6-dimethoxyphenyl)2(PMe₃)2]

There total 1 articles about trans-[Ni(2,6-dimethoxyphenyl)2(PMe₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 2785-97-9
(2,6-dimethoxyphenyl)lithium

: 20087-67-6
dichlorobis(trimethylphosphine)nickel

: 79973-29-8
trans-[Ni(2,6-dimethoxyphenyl)2(PMe₃)2]

Guidance literature:: In diethyl ether; Ni-complex reacted with excess of ligand in Et2O; according to K. Oguro, M. Wada, and N. Sonoda, J. Organomet. Chem., 1979, 165, C13; elem. anal.;

Reference yield: 65.0%

: 79973-29-8
trans-[Ni(2,6-dimethoxyphenyl)2(PMe₃)2]

: 7789-20-0
water-d2

: trans-[Ni(C₆H₃(OMe)2-2,6)2(PMe₂(CH₂D))2]

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; to soln. of Ni-complex in dry Et2O added 15% n-hexane soln. of 3 equiv of n-BuLi at 0°C under N2, stirred for 4 h at room temp., D2O added at 0°C, stirred for 0.5 h; Et2O added, washed with water, solvents removed under reduced pressure,recrystd. from MeOH;

Reference yield: 33.0%

: 128-08-5
N-Bromosuccinimide

: 79973-29-8
trans-[Ni(2,6-dimethoxyphenyl)2(PMe₃)2]

: 83459-96-5
trans-[Ni(3,5-dibromo-2,6-dimethoxyphenyl)2(PMe₃)2]

Guidance literature:: In acetone; to soln. of Ni-complex in acetone added soln. of 5 equiv of N-bromosuccinimide in acetone at 0°C, stirred for 1 h at 0°C, MeOH added, stirred for 0.5 h at 0°C; recrystd. from ethyl methyl ketone; elem. anal.;