Me₅In₃(1,1,2,2-tetraphenylethane-1,2-diolate)2

Base Information

• Chemical Name: Me₅In₃(1,1,2,2-tetraphenylethane-1,2-diolate)2
• CAS No.: 940867-29-8
• Molecular Formula: C₅₇H₅₅In₃O₄
• Molecular Weight: 1148.52
• Mol file: 940867-29-8.mol

Synonyms:

Chemical Property of Me₅In₃(1,1,2,2-tetraphenylethane-1,2-diolate)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Me₅In₃(1,1,2,2-tetraphenylethane-1,2-diolate)2

There total 1 articles about Me₅In₃(1,1,2,2-tetraphenylethane-1,2-diolate)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichloromethane (75-09-2) + trimethyl indium (3385-78-2) → Me5In3(1,1,2,2-tetraphenylethane-1,2-diolate)2 (940867-29-8)

Guidance literature:

In diethyl ether; dichloromethane; under inert atm., 2 equiv. of benzopinacol in CH2Cl2 was added to Et2O soln. of 3.3 equiv. of In-compd. at -78 °C, mixt. was allowed to warm to room temp. (2 h); storage at -25 °C for a week; further products were also formed;

DOI:10.1016/j.poly.2006.11.032

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + Me5In3(1,1,2,2-tetraphenylethane-1,2-diolate)2 (940867-29-8) → Me2In2(1,1,2,2-tetraphenylethane-1,2-diolate)2(THF)

Guidance literature:

With EtOH; In tetrahydrofuran; under inert atm., 1 equiv. of EtOH was added in THF to solid metal-compd., mixt. was set aside for ca. 24 h; other products were formed;

DOI:10.1016/j.poly.2006.11.032

upstream raw materials:

dichloromethane

trimethyl indium