[Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF₃SO₃)](B(3,5-bis(trifluoromethyl)phenyl)4)

Base Information

• Chemical Name: [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF₃SO₃)](B(3,5-bis(trifluoromethyl)phenyl)4)
• CAS No.: 1193781-96-2
• Molecular Formula: C₂₆H₁₉F₃N₅O₃RuS*C₃₂H₁₂BF₂₄
• Molecular Weight: 1502.82
• Mol file: 1193781-96-2.mol

Synonyms:

Chemical Property of [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF₃SO₃)](B(3,5-bis(trifluoromethyl)phenyl)4)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF₃SO₃)](B(3,5-bis(trifluoromethyl)phenyl)4)

There total 1 articles about [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF₃SO₃)](B(3,5-bis(trifluoromethyl)phenyl)4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

[RuCl(2,2':6':2''-terpyridine)(2,2'-bipyridine)](B(3,5-bis(trifluoromethyl)phenyl)4) (1193781-97-3) + silver trifluoromethanesulfonate (2923-28-6) → [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF3SO3)](B(3,5-bis(trifluoromethyl)phenyl)4) (1193781-96-2)

Guidance literature:

In CH₂Cl₂; byproducts: AgCl; (Ar); refluxing CH2Cl2 soln. of ruthenium compd. and silver compd. for 24 h; filtration, concg., addn. of pentane, filtration, washing with pentane, elem. anal.;

DOI:10.1021/ic901080r

Reference yield: 89.0%

sodium tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate dihydrate (455330-37-7) + [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF3SO3)](B(3,5-bis(trifluoromethyl)phenyl)4) (1193781-96-2) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(N,N-dimethylformamide)](B(3,5-bis(trifluoromethyl)phenyl)4)2

Guidance literature:

In dimethylformamide; stirring soln. of ruthenium compd. and borate deriv. in DMF for 5 min; addn. of cold water, filtration, washing with cold water, drying in vac., recrystn. by addn. of pentane to ethereal soln. under N2, elem. anal.;

DOI:10.1021/ic901080r

Reference yield:

diethyl ether (60-29-7,927820-24-4) + [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(CF3SO3)](B(3,5-bis(trifluoromethyl)phenyl)4) (1193781-96-2) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [Ru(2,2':6':2''-terpyridine)(2,2'-bipyridine)(diethyl ether)](B(3,5-bis(trifluoromethyl)phenyl)4)2

Guidance literature:

In CH₂Cl₂; byproducts: CF3SO3Na; (N2); addn. of borate deriv. to CH2Cl2 soln. of ruthenium compd., stirring for 30 min, filtration, addn. of diethyl ether; addn. of pentane, isolation of ppt., washing with pentane, dissolving indiethyl ether, ppn. with pentane, washing with pentane;

DOI:10.1021/ic901080r

upstream raw materials:

[RuCl(2,2':6':2''-terpyridine)(2,2'-bipyridine)](B(3,5-bis(trifluoromethyl)phenyl)4)

silver trifluoromethanesulfonate