1-(diphenylphosphino)-1'-([N-(4-pyridyl)methyl]carbamoyl)ferrocene

Base Information

Chemical Name:1-(diphenylphosphino)-1'-([N-(4-pyridyl)methyl]carbamoyl)ferrocene
CAS No.:1035458-00-4
Molecular Formula:C₂₉H₂₅FeN₂OP
Molecular Weight:504.351
Hs Code.:

Synonyms:

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Chemical Property of 1-(diphenylphosphino)-1'-([N-(4-pyridyl)methyl]carbamoyl)ferrocene

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Technology Process of 1-(diphenylphosphino)-1'-([N-(4-pyridyl)methyl]carbamoyl)ferrocene

There total 1 articles about 1-(diphenylphosphino)-1'-([N-(4-pyridyl)methyl]carbamoyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 3731-53-1
4-(aminomethyl)pyridine

: 173346-69-5
1′-(diphenylphosphino)ferrocene-1-carboxylic acid

: 1035458-00-4
1-(diphenylphosphino)-1'-([N-(4-pyridyl)methyl]carbamoyl)ferrocene

Guidance literature:: With N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide; 1-hydroxybenzotriazole; In dichloromethane; under Ar; N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide was added to ice-cooled soln. of Fe-contg. compd. and 1-hydroxybenzotriazole in CH2Cl2;stirring for 30 min at 0°C; addn. of 4-(aminomethyl)pyridine; st irring at room temp. overnight; extn. with aq. soln. of citric acid, satd. aq. NaHCO3, and brine; org. layer was dried over MgSO4 and evapd.; column chromy. (silica gel, eluting with CH2Cl2, then with CH2Cl2/MeOH (40:1); evapn. of the second fraction;
DOI:10.1039/b719334c

Reference yield: 82.0%

: cadmium(II) bromide hexahydrate

: 1035458-00-4
1-(diphenylphosphino)-1'-([N-(4-pyridyl)methyl]carbamoyl)ferrocene

: 64-19-7,77671-22-8
acetic acid

: 1035458-05-9
[CdBr3(Ph2P(ferrocene-1,1'-diyl)C(O)NHCH2(4-C5H4NH)-κP)]*H2O

Guidance literature:: In acetic acid; acetonitrile; aq. acetic acid; Cd-contg. compd. (0.05 mmol) was dissolved in a mixt. of acetic acid/water and dild. with acetic acid; the soln. was layered with CH3CN and withCH3CN soln. of Fe-contg. compd. (0.05 mmol); after 3 d, the soln. was filtered and layered with hexane; crystals wereisolated by suction, washed with MeOH, Et2O, and dried under reduced pr essure; elem. anal.;
DOI:10.1039/b719334c

Reference yield: 81.0%

: 67-66-3,8013-54-5
chloroform

: 1035458-00-4
1-(diphenylphosphino)-1'-([N-(4-pyridyl)methyl]carbamoyl)ferrocene

: mercury dibromide

: [HgBr2(μ-Ph2P(ferrocene-1,1'-diyl)C(O)NHCH2(4-C5H4N)]n*(chloroform)

Guidance literature:: In chloroform; a soln. of Fe-contg. compd. (0.05 mmol) in chloroform was layered with methanol and then with a methanol soln. of Hg-contg. compd. (0.05 mmol); standing for several days; soln. was filtered, crystals were washed with MeOH, Et2O, and dried under vac.; elem. anal.;
DOI:10.1039/b719334c