2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine

Base Information

• Chemical Name: 2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine
• CAS No.: 150196-53-5
• Molecular Formula: C₂₈H₃₆N₂O₇S₂
• Molecular Weight: 576.735
• Mol file: 150196-53-5.mol

Synonyms:

Chemical Property of 2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine

There total 17 articles about 2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

3-(2-methyl-1,3-benzothiazol-3-ium-3-yl)propane-1-sulfonate (56405-37-9) + 4-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)-benzaldehyde (66749-96-0) → 2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine (150196-53-5,150196-54-6)

Guidance literature:

With pyridine; In ethanol; Heating;

DOI:10.1007/BF02496216

Reference yield:

4-(bis(2-hydroxyethyl)amino)benzaldehyde (27913-86-6) → 2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine (150196-53-5,150196-54-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / Inert atmosphere; Reflux

1.2: 48 h / 70 °C

2.1: piperidine / ethanol / 2 h / Reflux

With piperidine; sodium hydride; In tetrahydrofuran; ethanol; mineral oil;

DOI:10.3762/bjoc.15.106

Reference yield:

4-(bis(2-hydroxyethyl)amino)benzaldehyde (27913-86-6) → 2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine (150196-53-5,150196-54-6)

Guidance literature:

Multi-step reaction with 3 steps

1.1: sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / Inert atmosphere; Reflux

1.2: 48 h / 70 °C

2.1: piperidine / ethanol / 2 h / Reflux

3.1: acetonitrile / 0.05 h / Irradiation

With piperidine; sodium hydride; In tetrahydrofuran; ethanol; acetonitrile; mineral oil;

DOI:10.3762/bjoc.15.106

upstream raw materials:

2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine

2-Methylbenzothiazole

3-(2-methyl-1,3-benzothiazol-3-ium-3-yl)propane-1-sulfonate

4-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)-benzaldehyde

Downstream raw materials:

2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine

2-{2-[4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl]ethenyl}-3-(3-sulphopropyl)benzothiazolium betaine