{(C₆H₅)3PAuMn(CO)5}

Base Information

• Chemical Name: {(C₆H₅)3PAuMn(CO)5}
• CAS No.: 14692-78-5
• Molecular Formula: C₂₃H₁₅AuMnO₅P
• Molecular Weight: 654.247
• Mol file: 14692-78-5.mol

Synonyms:

Chemical Property of {(C₆H₅)3PAuMn(CO)5}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(C₆H₅)3PAuMn(CO)5}

There total 4 articles about {(C₆H₅)3PAuMn(CO)5} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

{bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5} (52542-59-3) + tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate (53317-87-6) + Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13 (97349-41-2) → Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2 (129570-19-0) + AuMn*5CO*P(C6H5)3 = AuMn(CO)5(P(C6H5)3) (14692-78-5)

Guidance literature:

In tetrahydrofuran; N2 atmosphere; stirring (room temp. 20 h); removal of solvent (vac.), TLC (2/1 petroleum ether/CH2Cl2); IR and mass spectrometry;

Reference yield: 53.0%

methyl(triphenylphosphine)gold(I) + dimanganese decacarbonyl (10170-69-1) + pentacarbonylhydridomanganese (16972-33-1) → {(C6H5)3PAuMn(CO)5} (14692-78-5)

Guidance literature:

In benzene-d6; byproducts: methane; Irradiation (UV/VIS); a NMR tube containing Ph3PAuMe, HMn(CO)5, Mn2(CO)10 and C6D6 was prepared and sealed under vac., mixt. was irradiated with a 450-W broad-band UV lamp (Pyrex-filtered) for 3 min; (1)H NMR and IR spectral data;

DOI:10.1021/ja00265a018

Reference yield:

methyl(triphenylphosphine)gold(I) + dimanganese decacarbonyl (10170-69-1) + pentacarbonylhydridomanganese (16972-33-1) → tetracarbonylhydrido(triphenylphosphine)manganese (16925-29-4) + {(C6H5)3PAuMn(CO)5} (14692-78-5)

Guidance literature:

With triphenylphosphine; In benzene-d6; byproducts: methane; Irradiation (UV/VIS); a NMR tube with a soln. of reactants was prepd. and sealed under vac., irradiated with a 450-W broad-band UV lamp (Pyrex-filtered) for 2 min; ca. 63% of HMn(CO)4PPh3 was formed prior to photolysis, final Ph3PAuMn(CO)5 to HMn(CO)4PPh3 ratio 1:9; (1)H NMR monitoring;

DOI:10.1021/ja00265a018

upstream raw materials:

{bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5}

tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13

dimanganese decacarbonyl

Downstream raw materials:

Co(carbonyl)4(PPh₃)gold

((C₆H₅)3PAu)3Mn(CO)4

{((C₆H₅)3PAu)6Mn(CO)3}⁽¹⁺⁾*PF₆^(1-) = {((C₆H₅)3PAu)6Mn(CO)3}PF₆