cis-RuCl₂(CO)2(PPh₃)2

Base Information

• Chemical Name: cis-RuCl₂(CO)2(PPh₃)2
• CAS No.: 32240-63-4
• Molecular Formula: C₃₈H₃₀Cl₂O₂P₂Ru
• Molecular Weight: 752.579
• Mol file: 32240-63-4.mol

Synonyms:

Chemical Property of cis-RuCl₂(CO)2(PPh₃)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-RuCl₂(CO)2(PPh₃)2

There total 63 articles about cis-RuCl₂(CO)2(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tricarbonylbis(triphenylphosphine)ruthenium(0) (20332-49-4,14741-36-7) + nitrosylchloride (2696-92-6) → dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) (32240-63-4,29079-66-1,15709-57-6,36500-84-2,15709-73-6,14564-35-3) + trichloronitrosylbis(triphenylphosphine)ruthenium

Guidance literature:

In methanol; dichloromethane; addn. of NOCl soln. to Ru complex soln.; addn. of hot methanol; vigorously stirring; pptn.; centrifuging; washing (methanol, ether); drying (vac.); keeping centrifugate, 3-4h; pptn.; centrifuging; washing (methanol, ether); drying (vac.); elem. anal.;

Reference yield: 74.0%

{Ru(CO)2(NS2)(P(C6H5)3)2}(1+)*(SbCl6)(1-)={Ru(CO)2(NS2)(P(C6H5)3)2}(SbCl6) → dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) (32240-63-4,29079-66-1,15709-57-6,36500-84-2,15709-73-6,14564-35-3)

Guidance literature:

In dichloromethane; 2 h stirring, filtration, diln. in hot methanol, product filtered off, washed with methanol and diethyl ether, dried under vacuum; elem. anal.;

DOI:10.1016/S0020-1693(00)82208-2

Reference yield: 45.0%

trans-dichloro(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-O,O')bis(triphenylphosphine)ruthenium(II) → dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) (32240-63-4,29079-66-1,15709-57-6,36500-84-2,15709-73-6,14564-35-3) + chloro(carbonyl)(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)bis(triphenylphosphine)ruthenium(III)

Guidance literature:

With CO; In benzene; refuxing soln. of Ru-complex in benzene(CO atmosphere, 6 h); cooling, evapn. to dryness (reduced pressure), recrystn. (CH2Cl2-EtOH), washing (EtOH, light petroleum), drying (vac.); elem. anal.;

DOI:10.1016/S0277-5387(00)80353-8

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

trithiazyl trichloride

Ru(CO)3(PPh₃)3

RuCl₂(P(C₆H₅)3)(C₅H₃N(CH₂CHCH₂)2)

Downstream raw materials:

RuCl(CO)(C₅H₄NO)(P(C₆H₅)3)2

(Ru((C₆H₅)3P)2(C₆H₅CHNNCONH₂)(CO)Cl)

RuCl(C₅H₄NNH)(CO)(P(C₆H₅)3)2

(Ru((C₆H₅)3P)2(NO₂C₆H₄CHNNCONH₂)(CO)Cl)