bis(phenylthiolato-S)bis(tri-n-butylphosphine-P)nickel(II)

Base Information

Chemical Name:bis(phenylthiolato-S)bis(tri-n-butylphosphine-P)nickel(II)
CAS No.:168751-76-6
Molecular Formula:C₃₆H₆₄NiP₂S₂
Molecular Weight:681.674
Hs Code.:

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Chemical Property of bis(phenylthiolato-S)bis(tri-n-butylphosphine-P)nickel(II)

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Technology Process of bis(phenylthiolato-S)bis(tri-n-butylphosphine-P)nickel(II)

There total 4 articles about bis(phenylthiolato-S)bis(tri-n-butylphosphine-P)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 998-40-3
tributylphosphine

: 882-33-7
diphenyldisulfane

: 24510-67-6,168751-76-6
bis(phenylthiolato-S)bis(tri-n-butylphosphine-P)nickel(II)

Guidance literature:: In toluene; (Ar); addn. of phosphine deriv. to toluene soln. of nickel compd., stirring for 1 min, addn. of diphenyl disulfide, heating to 40°C for 1h; slow evap. at room temp. for few ds, isolation of crystals, elem. anal.;
DOI:10.1021/om1003732

Reference yield:

: nickel(II) chloride hexahydrate

: 998-40-3
tributylphosphine

: 930-69-8
sodium thiophenolate

: 24510-67-6,168751-76-6
bis(phenylthiolato-S)bis(tri-n-butylphosphine-P)nickel(II)

Guidance literature:: In methanol; molar ratio NiCl2:NaSPh:PBu3 = 1:2:2; recrystn from CH2Cl2;
DOI:10.1107/S0108270194014940

Reference yield:

: 998-40-3
tributylphosphine

: 3264-82-2
nickel(II) acetylacetonate

: 882-33-7
diphenyldisulfane

: 24510-67-6,168751-76-6
bis(phenylthiolato-S)bis(tri-n-butylphosphine-P)nickel(II)

Guidance literature:: In ⁽²⁾H₈-toluene; byproducts: OP(C4H9)3; addn. of phosphine deriv. and diphenyl disulfide to toluene-d8 soln. of nickel compd., heating to 40°C for 1 h; NMR;
DOI:10.1021/om1003732