11-(Perfluoro-n-hexyl)undecanol

Base Information

• Chemical Name: 11-(Perfluoro-n-hexyl)undecanol
• CAS No.: 134052-01-0
• Molecular Formula: C17H23F13O
• Molecular Weight: 490.348
• Hs Code.: 2905190098
• DSSTox Substance ID: DTXSID80895411
• Nikkaji Number: J424.384F
• Wikidata: Q82871619
• Mol file: 134052-01-0.mol

Synonyms:11-(Perfluoro-n-hexyl)undecanol;134052-01-0;12,12,13,13,14,14,15,15,16,16,17,17,17-tridecafluoroheptadecan-1-ol;SCHEMBL4867921;DTXSID80895411;LUTLJOIFXGWROU-UHFFFAOYSA-N;MFCD00236706;11-(Perfluorohex-1-yl)undecan-1-ol

Chemical Property of 11-(Perfluoro-n-hexyl)undecanol

Chemical Property:

• Boiling Point: 110 - 115 °C (1 mmHg)
• PSA: 20.23000
• LogP: 7.61850
• XLogP3: 8.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 15
• Exact Mass: 490.1541315
• Heavy Atom Count: 31
• Complexity: 529

Purity/Quality:

11-(Perfluorohex-1-yl)undecan-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CCCCCC(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)CCCCCO

Technology Process of 11-(Perfluoro-n-hexyl)undecanol

There total 9 articles about 11-(Perfluoro-n-hexyl)undecanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

10-Undecen-1-ol (112-43-6) + n-perfluorohexyl iodide (355-43-1) → 12,12,13,13,14,14,15,15,16,16,17,17,17-tridecafluoroheptadecane-1-ol (134052-01-0)

Guidance literature:

10-Undecen-1-ol; n-perfluorohexyl iodide; With 2,2'-azobis(isobutyronitrile); at 80 ℃; for 8h; Inert atmosphere;

With zinc; In ethanol; for 0.25h;

With acetic acid; In ethanol; for 5h; Reflux;

Reference yield: 76.0%

2-iodo-1-perfluorohexyl-11-undecanol (159142-57-1) → 12,12,13,13,14,14,15,15,16,16,17,17,17-tridecafluoroheptadecane-1-ol (134052-01-0)

Guidance literature:

With water; nickel dichloride; zinc; In tetrahydrofuran; for 1.5h; Ambient temperature;

DOI:10.1016/0022-1139(93)02993-O

Reference yield:

12,12,13,13,14,14,15,15,16,16,17,17,17-tridecafluoroheptadec-10-enol (117543-54-1) → 12,12,13,13,14,14,15,15,16,16,17,17,17-tridecafluoroheptadecane-1-ol (134052-01-0)

Guidance literature:

With hydrogenchloride; zinc; In ethanol; at 65 - 70 ℃; for 2h;

upstream raw materials:

2-iodo-1-perfluorohexyl-11-undecanol

acide 12,12,13,13,14,14,15,15,16,16,17,17,17-tridecafluoroheptadecanoique

12,12,13,13,14,14,15,15,15,16,16,17,17,17-tridecafluorheptadecansaeure-methylester

Methyl 10-undecenoate

Downstream raw materials:

[2,3-Bis-(12,12,13,13,14,14,15,15,16,16,17,17,17-tridecafluoro-heptadecyloxy)-propoxymethyl]-benzene

<2-(F-hexyl)-undecyl>dimorpholinophosphoramidate