1,2-Benzenediamine, N,N'-bis(trimethylsilyl)-

Base Information

• Chemical Name: 1,2-Benzenediamine, N,N'-bis(trimethylsilyl)-
• CAS No.: 13435-10-4
• Molecular Formula: C12H24N2Si2
• Molecular Weight: 252.507
• DSSTox Substance ID: DTXSID40392698
• Nikkaji Number: J793.109C
• Wikidata: Q82191071
• Mol file: 13435-10-4.mol

Synonyms:13435-10-4;1,2-Benzenediamine, N,N'-bis(trimethylsilyl)-;bis(tri methylsilylamino)benzene;SCHEMBL6751579;DTXSID40392698;ZHUVIWIIJHUEFI-UHFFFAOYSA-N;1,2-Bis(trimethylsilylamino)benzene;1,2-Benzenediamine, 2TMS derivative;1,2-Phenylenediamine, N,N'-di(trimethylsilyl)-

Chemical Property of 1,2-Benzenediamine, N,N'-bis(trimethylsilyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 252.14780184
• Heavy Atom Count: 16
• Complexity: 194

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)NC1=CC=CC=C1N[Si](C)(C)C

Technology Process of 1,2-Benzenediamine, N,N'-bis(trimethylsilyl)-

There total 2 articles about 1,2-Benzenediamine, N,N'-bis(trimethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

chloro-trimethyl-silane (75-77-4) + 1,2-diamino-benzene (95-54-5) → 1,2-bis(trimethylsilylamino)benzene (13435-10-4)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 20 ℃; Cooling with ice; Reflux; Inert atmosphere; Schlenk technique;

DOI:10.1515/mgmc-2021-0007

Reference yield:

→ 1,2-bis(trimethylsilylamino)benzene (13435-10-4)

Guidance literature:

DOI:10.1021/ja00707a019

Reference yield: 91.0%

Mo(=NPh)2(Cl)2(DME) + 1,2-bis(trimethylsilylamino)benzene (13435-10-4) → Mo(=NPh)(aniline)(Cl)2(o-(Me3SiN)2C6H4)

Guidance literature:

In hexane; Ar-atmosphere; stirring soln. of ligand (2 equivs.) with Mo-complex for 24 h at room temp.; collection (filtration), washing (hexane, Et2O); elem. anal.;

DOI:10.1021/om990124o

upstream raw materials:

chloro-trimethyl-silane

1,2-diamino-benzene

Downstream raw materials:

2-chloro-2,2'-dicyclohexyl-1'-trimethylsilanyl-2,3,2',3'-tetrahydro-1'H-[1,2']bi[benzo[1,3,2]diazasilolyl]

(C₆H₄N₂(C₆H₅P)2)2

C₂₄H₁₉Cl₂N₂P₃

(C₆H₄N₂)(PC₆H₅)3C₆H₄(NH)2