Technology Process of (NC4H2(CH3)CH2CH(OH)C6H4OCH3)Fe(C5H5)
There total 1 articles about (NC4H2(CH3)CH2CH(OH)C6H4OCH3)Fe(C5H5) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium;
In
tetrahydrofuran; cyclohexane;
byproducts: dibenzyl; under Ar; Li-contg. compd. (1.4 mmol) in cyclohexane was added to an Ar-satd. THF soln. of Fe-contg. compd. (1.05 mmol) and TMEDA (0.20 mmol) at-78°C; stirring for 1.5 h at -78°C; p-MeOPhCHO (1.46 mol) was added; stirring for 1.5 h; the mixt. was warmed to room temp. and poured onto water; extn. with CH2Cl2, drying over MgSO4 and solvent removal; column chromy.; elem. anal.;
DOI:10.1016/j.jorganchem.2003.11.038
- Guidance literature:
-
In
tetrahydrofuran;
Irradiation (UV/VIS); under Ar; W(CO)6 in THF photolysed (200 W high-pressure Hg lamp) for 2 h; treated with Fe complex; stirred at room temp. for 2 h; solvent removed; column chromd. (silica gel, CHCl3); crystd. from CHCl3-hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2004.09.083
