1,3-Dioxolane, 2-[(4-nitrophenyl)methyl]-

Base Information

Chemical Name:1,3-Dioxolane, 2-[(4-nitrophenyl)methyl]-
CAS No.:134485-50-0
Molecular Formula:C10H11NO4
Molecular Weight:209.202
Hs Code.:
DSSTox Substance ID:DTXSID10464730
Wikidata:Q82290188
Mol file:134485-50-0.mol

Synonyms:2-[(4-nitrophenyl)methyl]-1,3-dioxolane;1,3-Dioxolane, 2-[(4-nitrophenyl)methyl]-;134485-50-0;SCHEMBL8543345;DTXSID10464730;DNFLWMOAKGVPAV-UHFFFAOYSA-N

Suppliers and Price of 1,3-Dioxolane, 2-[(4-nitrophenyl)methyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 1,3-Dioxolane, 2-[(4-nitrophenyl)methyl]-

Chemical Property:

XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:209.06880783
Heavy Atom Count:15
Complexity:214

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1COC(O1)CC2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of 1,3-Dioxolane, 2-[(4-nitrophenyl)methyl]-

There total 4 articles about 1,3-Dioxolane, 2-[(4-nitrophenyl)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 764-48-7
ethyleneglycol vinyl ether

: 586-78-7
para-nitrophenyl bromide

: 19073-15-5
2-(4-nitrophenyl)-2-methyl-1,3-dioxolane

: 134485-50-0
2-<(4-nitrophenyl)methyl>-1,3-dioxolane

Guidance literature:: With potassium carbonate; (1RS,2RS,3SR,4SR)-1,2,3,4-tetrakis((diphenylphosphanyl)methyl)cyclopentane; bis(η3-allyl-μ-chloropalladium(II)); In N,N-dimethyl-formamide; at 130 ℃; for 20h;
DOI:10.1055/s-2004-829063

Reference yield: 60.0%

: 1460-05-5
p-nitrophenylacetaldehyde

: 107-21-1
ethylene glycol

: 134485-50-0
2-<(4-nitrophenyl)methyl>-1,3-dioxolane

Guidance literature:: With calcium sulfate; Rexyn 101 (H) cation-exchange resin; In dichloromethane; for 24h; Ambient temperature;
DOI:10.1021/ja00014a039

Reference yield:

: 100-13-0
4-nitrostyrene

: 134485-50-0
2-<(4-nitrophenyl)methyl>-1,3-dioxolane

Guidance literature:: Multi-step reaction with 2 steps

1: 50 percent / Pb(OAc)4, TFA / CH₂Cl₂ / 3 h / Ambient temperature

2: 60 percent / Rexyn 101 (H) cation-exchange resin, CaSO₄ / CH₂Cl₂ / 24 h / Ambient temperature

With lead(IV) acetate; calcium sulfate; Rexyn 101 (H) cation-exchange resin; trifluoroacetic acid; In dichloromethane;
DOI:10.1021/ja00014a039