RhCOCl((C₆H₅)4CH₂AsP)2PtCl₂

Base Information

• Chemical Name: RhCOCl((C₆H₅)4CH₂AsP)2PtCl₂
• CAS No.: 97112-55-5
• Molecular Formula: C₅₁H₄₄As₂Cl₃OP₂PtRh
• Molecular Weight: 1289.04
• Mol file: 97112-55-5.mol

Synonyms:

Chemical Property of RhCOCl((C₆H₅)4CH₂AsP)2PtCl₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of RhCOCl((C₆H₅)4CH₂AsP)2PtCl₂

There total 3 articles about RhCOCl((C₆H₅)4CH₂AsP)2PtCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

RhCOBr((C6H5)4CH2AsP)2PtBr2 (97112-56-6) → RhCOCl((C6H5)4CH2AsP)2PtCl2 (97112-55-5)

Guidance literature:

With NaCl; In methanol; dichloromethane; water; an excess of NaCl in H2O-MeOH was added to a soln. of complex in CH2Cl2, the mixt. was stirred for 2 h; evapd., filtered, washed with H2O and MeOH, recrystd. from CH2Cl2/Et2O and vac.-dried;

DOI:10.1021/om00127a024

Reference yield: 21.0%

{cis-Cl2(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl} (88867-59-8,88928-90-9) + <(Diphenylarsino)methyl>diphenylphosphan (69783-37-5) → RhCOCl((C6H5)4CH2AsP)2PtCl2 (97112-55-5) + ((diphenylphosphino)(diphenylarsino)methane)dichloroplatinum(II) (88867-61-2)

Guidance literature:

In dichloromethane; soln. of phosphine in CH2Cl2 was added to a soln. of complex in CH2Cl2;the mixt. was allowed to stand for 8 h; reduced in volume, MeOH was added, filtered off, filtrate was evapd., MeOH was added; recrystd. from CH2Cl2/Et2O;

DOI:10.1021/om00127a024

Reference yield: 19.0%

{cis-Cl2(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl} (88867-59-8,88928-90-9) → RhCOCl((C6H5)4CH2AsP)2PtCl2 (97112-55-5) + ((diphenylphosphino)(diphenylarsino)methane)dichloroplatinum(II) (88867-61-2)

Guidance literature:

In chloroform; soln. of complex in chloroform was heated under reflux for 2 h; reduced in volume, MeOH was added dropwise, ppt. was filtered off; filtrate was evapd., MeOH was added; filtered, recrystd. from CH2Cl2/Et2O; vac.-dried; elem. anal.;

DOI:10.1021/om00127a024

upstream raw materials:

RhCOBr((C₆H₅)4CH₂AsP)2PtBr₂

{cis-Cl₂(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl}

<(Diphenylarsino)methyl>diphenylphosphan