benzyl[(Z)-phenylmethylidene]ammoniumolate

Base Information

• Chemical Name: benzyl[(Z)-phenylmethylidene]ammoniumolate
• CAS No.: 77681-22-2
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.263
• Mol file: 77681-22-2.mol

Synonyms:

Chemical Property of benzyl[(Z)-phenylmethylidene]ammoniumolate

Chemical Property:

Purity/Quality:

BENZYL[(Z)-PHENYLMETHYLIDENE]AMMONIUMOLATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl[(Z)-phenylmethylidene]ammoniumolate

There total 18 articles about benzyl[(Z)-phenylmethylidene]ammoniumolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

benzaldehyde (100-52-7) + N-benzyl hydroxylalmine (622-30-0) → (Z)-N-benzylidenebenzylamine N-oxide (77681-22-2,3376-26-9,85225-56-5)

Guidance literature:

With magnesium sulfate; In dichloromethane; at 20 ℃; for 15h; Inert atmosphere;

DOI:10.1021/acs.joc.6b01499

Reference yield: 92.0%

dibenzylamine (103-49-1) → (Z)-N-benzylidenebenzylamine N-oxide (77681-22-2,3376-26-9,85225-56-5) + N,N-dibenzylhydroxylamine (621-07-8)

Guidance literature:

With Cumene hydroperoxide; 4 A molecular sieve; PVDF-membrane containing chiral Ti(IV); In chloroform-d1; at 60 ℃;

DOI:10.1016/j.tetlet.2004.07.142

Reference yield: 92.0%

→ (Z)-N-benzylidenebenzylamine N-oxide (77681-22-2,3376-26-9,85225-56-5)

Guidance literature:

With Oxone; sodium hydrogencarbonate; In water; acetone; at 40 ℃; for 2h;

upstream raw materials:

benzaldehyde

N-benzyl hydroxylalmine

dibenzylamine

N,N-dibenzylhydroxylamine

Downstream raw materials:

N-Benzyl-α-(butylamino)benzylaminyl-N-oxid

N-Benzyl-α-(methylamino)benzylaminyl-N-oxid

(3R,4S,5R)-2-benzyl-5-methyl-3-phenylisoxazolidine-4-carbaldehyde

trans-4-formyl-3-phenyl-2-(phenylmethyl)isoxazolidine