[(η5-C5Me5)IrCl]2(μ-H)(μ-S-2-hexyl)

Base Information

• Chemical Name: [(η5-C5Me5)IrCl]2(μ-H)(μ-S-2-hexyl)
• CAS No.: 1151942-86-7
• Molecular Formula: C₂₆H₄₄Cl₂Ir₂S
• Molecular Weight: 844.047
• Mol file: 1151942-86-7.mol

Synonyms:

Chemical Property of [(η5-C5Me5)IrCl]2(μ-H)(μ-S-2-hexyl)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-C5Me5)IrCl]2(μ-H)(μ-S-2-hexyl)

There total 1 articles about [(η5-C5Me5)IrCl]2(μ-H)(μ-S-2-hexyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

2,5-DIMETHYLTHIOPHENE (638-02-8) + ((C5(CH3)5)IrCl)2(μ-H)2 + hydrogen (1333-74-0) → bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) + [(η5-C5Me5)IrCl]2(μ-H)(μ-S-2-hexyl) (1151942-86-7,1152169-21-5) + [((η5-C5Me5)Ir)3(μ3-S)2]Cl2 + [((η5-C5Me5)Ir)3(μ3-S)2][(η5-C5Me5)IrCl3]2

Guidance literature:

In neat (no solvent); byproducts: n-hexane; in N2-filled drybox 2,5-dimethylthiophene was added to Ir-contg. compd.;the soln. was then freeze-pump-thaw degassed and H2 (1 atm) was added; heating in an oil bath at 120°C for 3 d; the soln. was concd. to dryness; the residue was dissolved in THF and eluted through aPateur pipet packed with silica using 20:80 THF:hexanes asthe eluent; the soln. was concd. to dryness; elem. anal.;

DOI:10.1021/om900114m

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + [(η5-C5Me5)IrCl]2(μ-H)(μ-S-2-hexyl) (1151942-86-7,1152169-21-5) + hydrogen sulfide (7783-06-4) → 2,5-DIMETHYLTHIOPHENE (638-02-8) + 2-hexanethiol (1679-06-7)

Guidance literature:

In toluene; by a react. of Ir-contg. compd. with H2S and HCl in toluene; detected by EI GC/MS;

DOI:10.1021/om900114m

upstream raw materials:

2,5-DIMETHYLTHIOPHENE

hydrogen

Downstream raw materials:

2,5-DIMETHYLTHIOPHENE

2-hexanethiol

Refernces