[(trifluoroacetate-κO)(dipyrido[3,2-a:2',3'-c]phenazine)(pentamethylcyclopentadienyl)iridium(III)] trifluoromethanate

Base Information

• Chemical Name: [(trifluoroacetate-κO)(dipyrido[3,2-a:2',3'-c]phenazine)(pentamethylcyclopentadienyl)iridium(III)] trifluoromethanate
• CAS No.: 906794-23-8
• Molecular Formula: CF₃O₃S*C₃₀H₂₅F₃IrN₄O₂
• Molecular Weight: 871.84
• Mol file: 906794-23-8.mol

Synonyms:

Chemical Property of [(trifluoroacetate-κO)(dipyrido[3,2-a:2',3'-c]phenazine)(pentamethylcyclopentadienyl)iridium(III)] trifluoromethanate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(trifluoroacetate-κO)(dipyrido[3,2-a:2',3'-c]phenazine)(pentamethylcyclopentadienyl)iridium(III)] trifluoromethanate

There total 1 articles about [(trifluoroacetate-κO)(dipyrido[3,2-a:2',3'-c]phenazine)(pentamethylcyclopentadienyl)iridium(III)] trifluoromethanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

dipyridil[3,2-a:2',3'-c]phenazine (19535-47-8) + [(pentamethylcyclopentadienyl)tris(acetone)iridium(III)] trifluoromethanate + [des-tyr1]-methionine enkephalin (61370-88-5) + trifluoroacetic acid (76-05-1) → [(trifluoroacetate-κO)(dipyrido[3,2-a:2',3'-c]phenazine)(pentamethylcyclopentadienyl)iridium(III)] trifluoromethanate (906794-23-8) + [(dipyrido[3,2-a:2',3'-c]phenazine)(pentamethylcyclopentadienyl)(glycyl-glycyl-phenylalanyl-methionine-κS)iridium(III)] trifluoromethanate

Guidance literature:

In methanol; dichloromethane; trifluoroacetic acid; Ar, Ir:peptide:dppz=1:1:1 molar ratio, to a soln. of Ir compd. (CH2Cl2/methanol) added dppz, refluxed for 2 h, a soln. of peptide in acid added,stirred for 18 h at 50°C; concd., pptd. (diethyl ether), ppt. washed, dried (vac.); elem. anal.;

DOI:10.1002/ejic.200500223

upstream raw materials:

dipyridil[3,2-a:2',3'-c]phenazine

[des-tyr¹]-methionine enkephalin

trifluoroacetic acid