racemic 1-Ph-2-tBu-3-SiMe₃-1H-2,1-benzazaborole

Base Information

• Chemical Name: racemic 1-Ph-2-tBu-3-SiMe₃-1H-2,1-benzazaborole
• CAS No.: 1613019-96-7
• Molecular Formula: C₂₀H₂₈BNSi
• Molecular Weight: 321.346
• Mol file: 1613019-96-7.mol

Synonyms:

Chemical Property of racemic 1-Ph-2-tBu-3-SiMe₃-1H-2,1-benzazaborole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of racemic 1-Ph-2-tBu-3-SiMe₃-1H-2,1-benzazaborole

There total 2 articles about racemic 1-Ph-2-tBu-3-SiMe₃-1H-2,1-benzazaborole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

chloro-trimethyl-silane (75-77-4) + [K(THF)](+1)*[1-Ph-2-tBu-1H-2,1-benzazaborolyl](-1) → racemic 1-Ph-2-tBu-3-SiMe3-1H-2,1-benzazaborole (1613019-96-7)

Guidance literature:

In tetrahydrofuran; for 0.5h;

DOI:10.1039/c4dt00812j

Reference yield:

[2-(CH=NtBu)C6H4]BPhCl → racemic 1-Ph-2-tBu-3-SiMe3-1H-2,1-benzazaborole (1613019-96-7)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium mirror / toluene / 72 h / 20 °C

2: 2 h / 20 °C

3: tetrahydrofuran / 0.5 h

With potassium mirror; In tetrahydrofuran; toluene;

DOI:10.1039/c4dt00812j

upstream raw materials:

chloro-trimethyl-silane