{Ru(CO)ClH(3,5-dimethylpyrazole)(P(p-tolyl)3)2}

Base Information

Chemical Name:{Ru(CO)ClH(3,5-dimethylpyrazole)(P(p-tolyl)3)2}
CAS No.:106564-60-7
Molecular Formula:C₄₈H₅₁ClN₂OP₂Ru
Molecular Weight:870.416
Hs Code.:

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Chemical Property of {Ru(CO)ClH(3,5-dimethylpyrazole)(P(p-tolyl)3)2}

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Technology Process of {Ru(CO)ClH(3,5-dimethylpyrazole)(P(p-tolyl)3)2}

There total 1 articles about {Ru(CO)ClH(3,5-dimethylpyrazole)(P(p-tolyl)3)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 85264-33-1
1-(Hydroxymethyl)-3,5-dimethylpyrazole

: carbonylchlorohydridobis(tri-p-tolylphosphine)ruthenium(II)

: 106564-60-7
{Ru(CO)ClH(3,5-dimethylpyrazole)(P(p-tolyl)3)2}

Guidance literature:: In ethanol; to suspn. of Ru(CO)ClH(P(C6H4Me-p)3)2 in EtOH at ca. 40°C added 1 equiv. of 1-hydroxymethyl-3,5-dimethylpyrazole in EtOH, stirred for 1 h; concd., solid filtered off, washed with C6H6, acetone, and Et2O, dried under vac.; elem. anal.;
DOI:10.1039/DT9870000183

Reference yield: 78.0%

: 106564-60-7
{Ru(CO)ClH(3,5-dimethylpyrazole)(P(p-tolyl)3)2}

: 922-67-8
propynoic acid methyl ester

: 115462-04-9
((p-tolyl)3P)2(3,5-dimethylpyrazole)(CO)ClRuCHCHCOOCH₃

Guidance literature:: In dichloromethane; reflux, 4 h; evapn. to dryness, washing with Et2O, dissoln. in CH2Cl2, pptn. with petroleum ether, washing with Et2O; elem. anal.;
DOI:10.1021/om00099a014

Reference yield: 70.0%

: 106564-60-7
{Ru(CO)ClH(3,5-dimethylpyrazole)(P(p-tolyl)3)2}

: 536-74-3
phenylacetylene

: 108296-48-6
Ru(CO)Cl(CHCHC₆H₅)((CH₃)2C₃HNNH)(P(C₆H₄CH₃)3)2

Guidance literature:: In dichloromethane; an excess of phenylacetylene was added to a soln. of the Ru complex, the mixt. was refluxed for 2 h, then concd., CH2Cl2 and petroleum ether were added, the ppt. was sepd., washed with EtOH and petroleum ether; purified by recrystallization from CH2Cl2 and petroleum ether; identified by elem. anal., IR and NMR spectra;