(η3-CH2CMeCH2)Pt(PPh3)Cl

Base Information

Chemical Name:(η3-CH2CMeCH2)Pt(PPh3)Cl
CAS No.:35770-10-6
Molecular Formula:C₂₂H₂₂ClPPt
Molecular Weight:547.923
Hs Code.:

Synonyms:

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Chemical Property of (η3-CH2CMeCH2)Pt(PPh3)Cl

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Technology Process of (η3-CH2CMeCH2)Pt(PPh3)Cl

There total 1 articles about (η3-CH2CMeCH2)Pt(PPh3)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 35770-44-6
(2-methylallyl)platinum chloride dimer

: {trans-palladium(II)Cl(PPh₃)2C(2-pyridyl)N(Me)}

: 35770-10-6
(η3-CH2CMeCH2)Pt(PPh3)Cl

: {cis-palladium(II)(Cl)2(PPh3)C(2-pyridyl)N(Me)Pt(II)(η3-2-MeC3H4)}

Guidance literature:: In benzene; The imino(2-pyridyl)methylpalladium(II)-complex is added to a soln. of the dimeric Pt(II)-complex in benzene, stirring for a few minutes at room temp., a clear yellow soln. is obtained, which is set aside for 6-7 h.; pptn. of a yellow solid, filtn., reprecipitation from CH2Cl2/Et2O, elem. anal., addn. of hexane to the mother liquor from first pptn., recrystn. (1,2-dichloroethane/hexane), (PtCl(η3-2-MeC3H4)(PPh3)) is obtained;
DOI:10.1016/S0020-1693(00)80494-6

Reference yield: 80.0%

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 26042-63-7
silver(I) hexafluorophosphate

: 35770-10-6
(η3-CH2CMeCH2)Pt(PPh3)Cl

: 79730-87-3
{(η3-CH2CMeCH2)Pt(PPh3)(CH2=CHPh)}PF6

Guidance literature:: In dichloromethane; acetone; byproducts: AgCl; acetone soln. of AgPF6 added to a CH2Cl2 soln. kept at 0°C contg. Pt-complex and olefin; AgCl filtered, soln. concd., hexane added to residue, this soln. kept in refrigerator overnight; elem. anal.;
DOI:10.1016/S0022-328X(00)85789-7

Reference yield:

: 26042-63-7
silver(I) hexafluorophosphate

: 35770-10-6
(η3-CH2CMeCH2)Pt(PPh3)Cl

: 766-90-5
cis-1-phenyl-1-propylene

: 95189-88-1
{(η3-CH2CMeCH2)Pt(PPh3)((Z)-MeCH=CHPh)}PF6

Guidance literature:: In dichloromethane-d2; byproducts: AgCl; pptd. AgCl filtered off; pure product not obtained, detected by (1)H-NMR;
DOI:10.1021/ja00218a031