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Ru((13)CO)4(P(CH3)2C6H5)

Base Information
  • Chemical Name:Ru((13)CO)4(P(CH3)2C6H5)
  • CAS No.:157741-64-5
  • Molecular Formula:C12H11O4PRu
  • Molecular Weight:355.217
  • Hs Code.:
Ru(<sup>(13)</sup>CO)4(P(CH<sub>3</sub>)2C<sub>6</sub>H<sub>5</sub>)

Synonyms:

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Chemical Property of Ru((13)CO)4(P(CH3)2C6H5)
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Technology Process of Ru((13)CO)4(P(CH3)2C6H5)

There total 4 articles about Ru((13)CO)4(P(CH3)2C6H5) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
In hexane; Irradiation (UV/VIS); soln. Ru-complex/hexane under atmosphere of (13)CO irradiated (high pressure Hg lamp, 8 h), (13)CO atmosphere refreshed once, further irradiation (5 h), soln. had turned colorless, soln. placed under N2, addn. PMe2Ph, soln. stirred 18 h; orange soln. concd. (vac.), column chromy. (Kieselgel 60), elution with1. hexane/CH2Cl2 (19/1) gave yellow fraction of Ru3(CO)12, 2. hexane/CH2Cl2 (40/6) gave product;
DOI:10.1021/om00020a046
Guidance literature:
Multi-step reaction with 2 steps
1: CO / petroleum ether
2: hexane
With CO; In hexane;
Guidance literature:
In hexane; soln. stirred under (13)CO at 45°C for 18 h; crystn. (hexane) at -60°C, IR spect.;
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