trans-2,6-dimethyl-2-nitrocyclohexanone

Base Information

Chemical Name:trans-2,6-dimethyl-2-nitrocyclohexanone
CAS No.:80594-91-8
Molecular Formula:C₈H₁₃NO₃
Molecular Weight:171.196
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-2,6-dimethyl-2-nitrocyclohexanone

Chemical Property:

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Technology Process of trans-2,6-dimethyl-2-nitrocyclohexanone

There total 5 articles about trans-2,6-dimethyl-2-nitrocyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2816-57-1
2,6-dimethylcyclohexanone

: 80594-91-8
trans-2,6-dimethyl-2-nitrocyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent Chromat_. / triethylamine / dimethylformamide / 120 h / 110 °C

2: 8.5 percent / NO₂BF₄ / acetonitrile / 1.) -25 deg C, 1 h, 2.) RT, 2 h

With nitronium tetrafluoborate; triethylamine; In N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo00346a006

Reference yield:

: 19980-35-9
1-trimethylsilyloxy-2-methyl-1-cyclohexene

: 80594-91-8
trans-2,6-dimethyl-2-nitrocyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: NO₂BF₄ / acetonitrile / 1.) -25 deg C, 1 h, 2.) RT, 3 h

2: 1.) n-butylliyhium, diisopropylamine, hexamethylphosphoric triamide / 1.) THF, -78 deg C, 30 min, 2a.) -78 deg C, 30 min, 2b.) from 0 deg C to 10 deg C, 3 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; nitronium tetrafluoborate; diisopropylamine; In acetonitrile;
DOI:10.1021/jo00346a006

Reference yield:

: 1196-73-2
1-acetoxy-2-methylcyclohexene

: 80594-91-8
trans-2,6-dimethyl-2-nitrocyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: 21 percent / conc. aq. HNO₃, acetic anhydride / 2 h / 15 - 22 °C

2: 1.) n-butylliyhium, diisopropylamine, hexamethylphosphoric triamide / 1.) THF, -78 deg C, 30 min, 2a.) -78 deg C, 30 min, 2b.) from 0 deg C to 10 deg C, 3 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; nitric acid; acetic anhydride; diisopropylamine;
DOI:10.1021/jo00346a006