endo-7-oxabicyclo{2.2.1}hept-5-en-2-yl benzoate

Base Information

Chemical Name:endo-7-oxabicyclo{2.2.1}hept-5-en-2-yl benzoate
CAS No.:148207-19-6
Molecular Formula:C₁₃H₁₂O₃
Molecular Weight:216.236
Hs Code.:

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Chemical Property of endo-7-oxabicyclo{2.2.1}hept-5-en-2-yl benzoate

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Technology Process of endo-7-oxabicyclo{2.2.1}hept-5-en-2-yl benzoate

There total 2 articles about endo-7-oxabicyclo{2.2.1}hept-5-en-2-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 114370-27-3,114511-69-2,137819-88-6,141900-15-4
(1RS,2RS,4RS)-7-oxabicyclo< 2.2.1> hept-5-en-2-ol

: 98-88-4
benzoyl chloride

: 137861-85-9,148207-19-6
endo-7-oxabicyclo{2.2.1}hept-5-en-2-yl benzoate

Guidance literature:: With pyridine; dmap; In dichloromethane; at 20 ℃; for 15h;
DOI:10.1039/c39910001334

Reference yield:

: 95530-78-2
7-oxabicyclo[2.2.1]hept-5-en-2-one

: 137861-85-9,148207-19-6
endo-7-oxabicyclo{2.2.1}hept-5-en-2-yl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: NaBH₄ / methanol

2: 92 percent / pyridine, 4-dimethylaminopyridine (DMAP) / CH₂Cl₂ / 15 h / 20 °C

With pyridine; dmap; sodium tetrahydroborate; In methanol; dichloromethane;
DOI:10.1039/c39910001334

Reference yield: 51.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 137861-85-9,148207-19-6
endo-7-oxabicyclo{2.2.1}hept-5-en-2-yl benzoate

: di(μ-hydrido)(7-oxabicyclo{2.2.1}hept-5-yn-2-endo-yl benzoate)-triangulo-tris(tricarbonylruthenium)(3Ru-Ru)

Guidance literature:: In n-heptane; soln. of 7-oxabicyclo(2.2.1)hept-5-en-2-endo-yl benzoate in heptane was degassed by bubbling He for 15 min at 20°C; Ru3(CO)12 was added; soln. was heated to 95-100°C under Ar for 3 h 45 min and then cooled to 20°C; solvent was evapd. in vac.; residue was taken with CH2Cl2 and silica gel; solvent was evapd.; chromy. (silica gel, CH2Cl2); ppt. was recrystd. from CH2Cl2-light petroleum at -18°C; elem. anal.;