(C₆H₅)2PCH₂CH₂N(CH₃)2Pt(C⁽²⁾H₃)2

Base Information

• Chemical Name: (C₆H₅)2PCH₂CH₂N(CH₃)2Pt(C⁽²⁾H₃)2
• CAS No.: 484065-57-8
• Molecular Formula: C₁₈H₂₆NPPt
• Molecular Weight: 488.417
• Mol file: 484065-57-8.mol

Synonyms:

Chemical Property of (C₆H₅)2PCH₂CH₂N(CH₃)2Pt(C⁽²⁾H₃)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₅)2PCH₂CH₂N(CH₃)2Pt(C⁽²⁾H₃)2

There total 1 articles about (C₆H₅)2PCH₂CH₂N(CH₃)2Pt(C⁽²⁾H₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(2,5-norbornadiene)Pt(CD3)2 (240123-30-2) + N,N-dimethyl-2-diphenylphosphinoethylamine (29679-67-2) → [(κ(2)-P,N)-Me2NCH2CH2PPh2]Pt(CD3)2 (484065-57-8)

Guidance literature:

synthesis according to ref. (Angew. Chem., Int. Ed. Engl. 1994, vol. 33,p. 317);

DOI:10.1021/om990123w

Reference yield: 99.0%

[(κ(2)-P,N)-Me2NCH2CH2PPh2]Pt(CD3)2 (484065-57-8) + methylene chloride (74-87-3) → [(κ(2)-P,N)-Ph2PCH2CH2NMe2]PtMe(CD3)3Cl (484065-61-4)

Guidance literature:

In benzene-d6; all manipulations under Ar atm.; MeCl bubbled through soln. of Pt compd., then heated to .60°C for 24 h;

Reference yield:

(C6H5)2PCH2CH2N(CH3)2Pt(C(2)H3)2 (484065-57-8) → ((C6H5)2PCH2CH2N(CH3)2)2Pt(C(2)H3)2

Guidance literature:

With (CH₃(CH₂)3)2SnH₂; In benzene-d6; (Ar); addn. of stannane to a soln. of platinum complex in C6D6 at room temp., keeping for 90 min, addn. of stannane, keeping for 90 min; not isolated, detected by NMR;

DOI:10.1016/j.ica.2004.01.035

upstream raw materials:

(2,5-norbornadiene)Pt(CD₃)2

N,N-dimethyl-2-diphenylphosphinoethylamine

Downstream raw materials:

[(κ(2)-P,N)-Ph2PCH2CH2NMe2]PtMe(CD3)3Cl

Refernces