bibenzyl/cannabicitran

Base Information

• Chemical Name: bibenzyl/cannabicitran
• CAS No.: 120467-15-4
• Molecular Formula: C₂₄H₂₈O₂
• Molecular Weight: 348.485
• Mol file: 120467-15-4.mol

Synonyms:

Chemical Property of bibenzyl/cannabicitran

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bibenzyl/cannabicitran

There total 3 articles about bibenzyl/cannabicitran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

dihydropinosylvin (14531-52-3) + (E/Z)-3,7-dimethyl-2,6-octadienal (5392-40-5,96680-15-8) → 2-methyl-2-(4-methyl-pent-3-enyl)-7-phenethyl-2H-chromen-5-ol + bibenzyl/cannabicitran (120467-15-4)

Guidance literature:

With ethylenediamine diacetic acid; In para-xylene; for 10h; Inert atmosphere; Reflux;

DOI:10.5012/bkcs.2011.32.2.566

Reference yield:

1,3-dimethoxy-5-(2-phenylethyl)benzene (78916-50-4) → bibenzyl/cannabicitran (120467-15-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 71 percent / BBr₃ / CH₂Cl₂ / 1.) -70 deg C, 2.) room temp., 2 h

2: 6.3 mg / 2,6-di-t-butyl pyridine / 5.5 h / 160 °C

With 2,6-di-tert-butyl-pyridine; boron tribromide; In dichloromethane;

DOI:10.1039/P19880001263

Reference yield:

dihydropinosylvin (14531-52-3) + (E/Z)-3,7-dimethyl-2,6-octadienal (5392-40-5,96680-15-8) → (+/-)-bibenzyl/p-cannabichromene hybrid (120467-13-2) + (+/-)-bibenzyl/o-cannabichromene hybrid (120467-14-3) + (+/-)-bibenzyl/p-cannabicyclol hybrid (120467-16-5) + (+/-)-bibenzyl/o-cannabicyclol hybrid (120467-17-6) + bibenzyl/cannabicitran (120467-15-4)

Guidance literature:

With 2,4,6-trimethyl-pyridine; at 160 ℃; for 5.5h; Product distribution; various bases;

DOI:10.1039/P19880001263

upstream raw materials:

dihydropinosylvin

(E/Z)-3,7-dimethyl-2,6-octadienal

1,3-dimethoxy-5-(2-phenylethyl)benzene