ethyldiphenylbismutane

Base Information

Chemical Name:ethyldiphenylbismutane
CAS No.:88372-75-2
Molecular Formula:C₁₄H₁₅Bi
Molecular Weight:392.254
Hs Code.:

Synonyms:

Suppliers and Price of ethyldiphenylbismutane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ethyldiphenylbismutane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ethyldiphenylbismutane

There total 2 articles about ethyldiphenylbismutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 811-49-4
ethyllithium

: 5153-28-6
diphenylbismuth(III) chloride

: 88372-75-2
ethyldiphenylbismutane

Guidance literature:: In diethyl ether; pentane; byproducts: LiCl, C6H5Bi(CH2CH3)2; react. under N2 in dry, N2-satd. solvents; dropwise addn. of Li-compd. in pentane to a stirred suspn. of Bi-compd. in ether (-70 to -65°C, 1 h), stirring for 0.5 h at -70°C, warming to room temp.; evapn. (vac.), reslurring of residue with benzine and decantation (3 times), evapn. of combined solns. (room temp., vac.), distn. of oily bismutane at 1E-1 to 1E-2 Torr; elem. anal.;

Reference yield: 39.0%

: 74-96-4
ethyl bromide

: 603-33-8
triphenylbismuthane

: 88372-75-2
ethyldiphenylbismutane

: 85824-65-3
diethyl(Ph)bismutine

Guidance literature:: With potassium; In tetrahydrofuran; byproducts: ethylbenzene; a THF soln. of Ph3Bi was treated with K under Ar, mixt. was stirred forseveral hours at 25°C, at -40°C EtBr was added slowly; PhEt and THF were removed in vacuo, residue extd. with n-pentane-toluene, ext. evapd., residue was purified by Kugelrohr distn. at 130°C; elem. anal. for Ph2BiEt, it was contaminated with a small amt. of PhBiEt2 according to mass spectral data;
DOI:10.1016/S0022-328X(00)99236-2