chloro(chloromethyl)methylphenylgermane

Base Information

• Chemical Name: chloro(chloromethyl)methylphenylgermane
• CAS No.: 134317-77-4
• Molecular Formula: C₈H₁₀Cl₂Ge
• Molecular Weight: 249.663
• Mol file: 134317-77-4.mol

Synonyms:

Chemical Property of chloro(chloromethyl)methylphenylgermane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of chloro(chloromethyl)methylphenylgermane

There total 1 articles about chloro(chloromethyl)methylphenylgermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyllithium (917-54-4) + dichloro(chloromethyl)phenylgermane (19089-97-5) → chloro(chloromethyl)methylphenylgermane (134317-77-4) + (chlromethyl)dimethyl(phenyl)germane (24486-57-5)

Guidance literature:

In diethyl ether; to a soln. of Ge-compd. in diethyl ether is added an etheral soln. of MeLi at -70°C during 2 h with stirring, then mixt. is allowed to warm to room temp. and stirred for 2 h under reflux (N2); ppt. is filtd. off and washed with petroleum ether, filtrate is evapd. to dryness (reduced pressure), residue is distd. in vac. (Vigreux column; 114-126°C/15 Torr), elem. anal.;

Reference yield: 90.0%

chloro(chloromethyl)methylphenylgermane (134317-77-4) + (chlromethyl)dimethyl(phenyl)germane (24486-57-5) + dichloro(chloromethyl)phenylgermane (19089-97-5) → acetoxy(acetoxymethyl)methylphenylgermane (134317-78-5)

Guidance literature:

With acetic acid; triethylamine; In toluene; to a soln. containing triethyl amine and a mixt. of the Ge-compds. in toluene is added dropwise glacial acetic acid, mixt. is stirred for 6 h under reflux (N2); ppt. is filtd. off, washed with petroleum ether, filtrate is evapd. to dryness, residue is distd. in vac. (Vigreux column), elem. anal.;

upstream raw materials:

methyllithium

dichloro(chloromethyl)phenylgermane

Downstream raw materials:

acetoxy(acetoxymethyl)methylphenylgermane