[Ni(CH₂CMe₂Ph)2(tmen)]

Base Information

Chemical Name:[Ni(CH₂CMe₂Ph)2(tmen)]
CAS No.:78054-46-3
Molecular Formula:C₂₆H₄₂N₂Ni
Molecular Weight:441.323
Hs Code.:

[Ni(CH<sub>2</sub>CMe<sub>2</sub>Ph)2(tmen)]

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Chemical Property of [Ni(CH₂CMe₂Ph)2(tmen)]

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Technology Process of [Ni(CH₂CMe₂Ph)2(tmen)]

There total 2 articles about [Ni(CH₂CMe₂Ph)2(tmen)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: nickel(II)bis(2,4-pentanedionate)(N,N,N,N-tetramethylethylenediamine)

: 62218-17-1
bis(2-methyl-2-phenylpropyl)magnesium

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 78054-46-3
[Ni(CH₂CMe₂Ph)2(tmen)]

Guidance literature:: In diethyl ether; at 0 - 20 ℃; for 2.5h; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1021/acs.organomet.0c00262

Reference yield:

: 14076-99-4,20154-73-8,36829-43-3
[nickel(II)(pyridine)4(chloride)2]

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 35293-35-7
2-methyl-2-phenyl-1-propylmagnesium chloride

: 78054-46-3
[Ni(CH₂CMe₂Ph)2(tmen)]

Guidance literature:: In diethyl ether; under oxygen-free nitrogen to stirred suspension of NiCl2(py)2 in diethyl ether at -6-°C added excess of tmen and Mg(CH2CMe2Ph)Cl, stirred for 5-10 min at room temp.; solvent removed under reduced pressure, residue extd. with cold light petroleum with some added tmen, centrifuged, removal of solvent and cooling at -30.degree, elem. anal.;

Reference yield:

: 366-18-7
[2,2]bipyridinyl

: 78054-46-3
[Ni(CH₂CMe₂Ph)2(tmen)]

: bipyridylbis(2-methyl-2-phenylpropyl)nickel(II)

Guidance literature:: In benzene; under oxygen-free nitrogen stirred for 10-15 min at room temp.; removal of solvent in vac., crystn. from diethyl ether, elem. anal.;