Nickel,dichlorotetrakis(pyridine)-

Base Information

• Chemical Name: Nickel,dichlorotetrakis(pyridine)-
• CAS No.: 14076-99-4
• Molecular Formula: C₂₀H₂₀Cl₂N₄Ni
• Molecular Weight: 446.002
• Mol file: 14076-99-4.mol

Synonyms:Dichlorotetrakis(pyridine)nickel;Dichlorotetrapyridinenickel; NSC 209792

Chemical Property of Nickel,dichlorotetrakis(pyridine)-

Chemical Property:

• Boiling Point: 106.4°Cat760mmHg
• Flash Point: 4.4°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Nickel,dichlorotetrakis(pyridine)-

There total 23 articles about Nickel,dichlorotetrakis(pyridine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

nickel(II) chloride hexahydrate → trans-dichlorotetrakis(pyridine)nickel(II) (14076-99-4,20154-73-8,36829-43-3)

Guidance literature:

With pyridine; an excess of ligand was added to salt in phosphate, room temp.; filtration; elem. anal.;

DOI:10.1016/S0020-1693(00)93522-9

Reference yield:

nickel dichloride (83864-14-6) → [nickel(II)(pyridine)4(chloride)2] (14076-99-4,20154-73-8,36829-43-3)

Guidance literature:

With pyridine; In solid; NiCl2 was placed in a desiccator into vapor of pyridine, chemisorption was effected in a few days term with repeated mortarring; elem. anal.;

DOI:10.1007/BF01983532

Reference yield:

Ni(2+)*2(CH3)2CNNHCOC6H5*2Cl(1-)=[Ni((CH3)2CNNHCOC6H5)2]Cl2 → [nickel(II)(pyridine)4(chloride)2] (14076-99-4,20154-73-8,36829-43-3)

Guidance literature:

With pyridine; In pyridine; byproducts: Me2CNNHCOC6H5; boiling;

DOI:10.1016/S0020-1693(00)90911-3

upstream raw materials:

pyridine

nickel dichloride

Downstream raw materials:

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

Dibutyl carbonate

di-n-butyl oxalate

tetracarbonyl nickel