PtCl(1,1'-binaphthane-2,2'-diyl 2,4-di-t-Bu-phenyl phosphite)(1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite(-1H))

Base Information

Chemical Name:PtCl(1,1'-binaphthane-2,2'-diyl 2,4-di-t-Bu-phenyl phosphite)(1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite(-1H))
CAS No.:1188508-71-5
Molecular Formula:C₆₈H₆₅ClO₆P₂Pt
Molecular Weight:1270.74
Hs Code.:

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Chemical Property of PtCl(1,1'-binaphthane-2,2'-diyl 2,4-di-t-Bu-phenyl phosphite)(1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite(-1H))

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Technology Process of PtCl(1,1'-binaphthane-2,2'-diyl 2,4-di-t-Bu-phenyl phosphite)(1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite(-1H))

There total 4 articles about PtCl(1,1'-binaphthane-2,2'-diyl 2,4-di-t-Bu-phenyl phosphite)(1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite(-1H)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 10025-99-7
potassium tetrachloroplatinate(II)

: 1188508-67-9
cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2]

: 1188508-71-5
PtCl(1,1'-binaphthane-2,2'-diyl 2,4-di-t-Bu-phenyl phosphite)(1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite(-1H))

Guidance literature:: In 2-methoxy-ethanol; (N2); using Schlenk techniques; dissolving of PtCl2(((t-Bu)2C6H2OP(OC10H6)2)2 in 2-methoxyethanol; heating at 135°C; cooling; concn. under vac., pptn. by addn. of hexanes; filtration; drying under vac., elem. anal.;
DOI:10.1021/om9003237

Reference yield: 54.0%

: 10025-99-7
potassium tetrachloroplatinate(II)

: 1110685-33-0,1188513-84-9,868638-25-9
(R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite

: 1188508-71-5
PtCl(1,1'-binaphthane-2,2'-diyl 2,4-di-t-Bu-phenyl phosphite)(1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite(-1H))

Guidance literature:: In m-xylene; (N2); using Schlenk techniques; suspending of (t-Bu)2C6H3OP(OC10H6)2 andK2PtCl4 (0.5 equiv.) in m-xylene; reflux at 135°C overnight; cooling; concn. under vac., pptn. by addn. of hexanes; filtration, drying under vac.;
DOI:10.1021/om9003237

Reference yield:

: 1110685-33-0,1188513-84-9,868638-25-9
(R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite

: 1188508-71-5
PtCl(1,1'-binaphthane-2,2'-diyl 2,4-di-t-Bu-phenyl phosphite)(1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite(-1H))

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane

2: 2-methoxy-ethanol

In dichloromethane; 2-methoxy-ethanol;
DOI:10.1021/om9003237