(S)-sec-phenethyl 2,2,2-trifluoroethyl carbonate

Base Information

Chemical Name:(S)-sec-phenethyl 2,2,2-trifluoroethyl carbonate
CAS No.:283585-00-2
Molecular Formula:C₁₁H₁₁F₃O₃
Molecular Weight:248.202
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-sec-phenethyl 2,2,2-trifluoroethyl carbonate

Chemical Property:

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Technology Process of (S)-sec-phenethyl 2,2,2-trifluoroethyl carbonate

There total 2 articles about (S)-sec-phenethyl 2,2,2-trifluoroethyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-89-8
2,2,2-trifluoroethanol

: 141037-03-8
(RS)-sec-phenethyl 1H-imidazole-1-carboxylate

: 283585-00-2
(S)-sec-phenethyl 2,2,2-trifluoroethyl carbonate

: (R)-sec-phenethyl 2,2,2-trifluoroethyl carbonate

Guidance literature:: 2,2,2-trifluoroethanol; (RS)-sec-phenethyl 1H-imidazole-1-carboxylate; With dmap; In dichloromethane; at 20 ℃; for 480h;

With Porcine Pancreas Lipase; poly(ethylene glycol); In di-isopropyl ether; 1,2-dichloro-benzene; at 45 ℃; for 216h; Title compound not separated from byproducts;
DOI:10.1016/S0957-4166(00)00068-9

Reference yield:

: 98-85-1,13323-81-4
1-Phenylethanol

: 283585-00-2
(S)-sec-phenethyl 2,2,2-trifluoroethyl carbonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 98 percent / CH₂Cl₂ / 4 h / 20 °C

2.1: DMAP / CH₂Cl₂ / 480 h / 20 °C

2.2: porcine pancreas lipase; poly(ethylene glycol), M_.W_. ca. 1500 / diisopropyl ether; 1,2-dichloro-benzene / 216 h / 45 °C

With dmap; In dichloromethane; 1.1: Condensation / 2.1: Condensation / 2.2: kinetic resolution;
DOI:10.1016/S0957-4166(00)00068-9