Os(B(OC₂H₅)(OC₂H₄OH))Cl(CO)(P(C₆H₅)3)2

Base Information

• Chemical Name: Os(B(OC₂H₅)(OC₂H₄OH))Cl(CO)(P(C₆H₅)3)2
• CAS No.: 709610-96-8
• Molecular Formula: C₄₁H₄₀BClO₄OsP₂
• Molecular Weight: 895.178
• Mol file: 709610-96-8.mol

Synonyms:

Chemical Property of Os(B(OC₂H₅)(OC₂H₄OH))Cl(CO)(P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Os(B(OC₂H₅)(OC₂H₄OH))Cl(CO)(P(C₆H₅)3)2

There total 1 articles about Os(B(OC₂H₅)(OC₂H₄OH))Cl(CO)(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Os(B(OC2H5)2)Cl(CO)(P(C6H5)3)2 (610270-34-3) + ethylene glycol (107-21-1) → Os(B(OC2H5)(OC2H4OH))Cl(CO)(P(C6H5)3)2 (709610-96-8) + Os(BOC2H4O)Cl(CO)(P(C6H5)3)2 (709610-97-9)

Guidance literature:

With Me₃SiCl; In tetrahydrofuran; mixt. of Os complex, C2H4(OH)2 and Me3SiCl (1 equiv.) stirred in THF for11 min; solvent removed slowly in vac.; solid collected on glass frit; washed with EtOH and hexane; mixt. of two Os complexes obtained;

DOI:10.1016/j.jorganchem.2004.02.011

Reference yield: 71.0%

Os(B(OC2H5)(OC2H4OH))Cl(CO)(P(C6H5)3)2 (709610-96-8) + Os(BOC2H4O)Cl(CO)(P(C6H5)3)2 (709610-97-9) + carbon monoxide (201230-82-2) → Os(BOC2H4O)Cl(CO)2(P(C6H5)3)2 (709610-98-0)

Guidance literature:

In tetrahydrofuran; mixt. of two Os complexes (molar ratio 1:1) dissolved in THF; CO bubbledthrough the soln. for 5 s; concd. in vac.; hexane added; ppt. collected on glass frit; washed with EtOH and hexane; elem. anal.;

DOI:10.1016/j.jorganchem.2004.02.011

upstream raw materials:

Os(B(OC₂H₅)2)Cl(CO)(P(C₆H₅)3)2

ethylene glycol

Downstream raw materials:

Os(BOC₂H₄O)Cl(CO)2(P(C₆H₅)3)2