(C₆H₁₁)3PBH(SC₆H₅)CO₂CH₃

Base Information

• Chemical Name: (C₆H₁₁)3PBH(SC₆H₅)CO₂CH₃
• CAS No.: 287923-11-9
• Molecular Formula: C₂₆H₄₂BO₂PS
• Molecular Weight: 460.469
• Mol file: 287923-11-9.mol

Synonyms:

Chemical Property of (C₆H₁₁)3PBH(SC₆H₅)CO₂CH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (C₆H₁₁)3PBH(SC₆H₅)CO₂CH₃

There total 2 articles about (C₆H₁₁)3PBH(SC₆H₅)CO₂CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

(C6H11)3PBHBrCO2CH3 (287923-07-3,288098-56-6,288098-57-7) + lithium thiophenoxide (2973-86-6) → (C6H11)3PBH(SC6H5)CO2CH3 (287923-11-9,288098-58-8)

Guidance literature:

In tetrahydrofuran; at 0° for 2 h;

DOI:10.1021/ja0011764

Reference yield: 54.0%

(C6H11)3PBHBrCO2CH3 (287923-07-3,288098-56-6,288098-57-7) + diphenyldisulfane (882-33-7) → (C6H11)3PBH(SC6H5)CO2CH3 (287923-11-9,288098-58-8)

Guidance literature:

With lithium 4,4'-di-tert-butylbiphenylide; TMEDA; In neat (no solvent); boron complex reacted with Li deriv. in TMEDA at -78° for 5 min and then with with iodomethane; racemic structure was confirmed by HPLC using chiral columns;

DOI:10.1021/ja0011764

upstream raw materials:

(C₆H₁₁)3PBHBrCO₂CH₃

lithium thiophenoxide

diphenyldisulfane