[RuCp(PPh₃)(PPr(i)2Me)(Cl)]

Base Information

• Chemical Name: [RuCp(PPh₃)(PPr(i)2Me)(Cl)]
• CAS No.: 214399-71-0
• Molecular Formula: C₃₀H₃₇ClP₂Ru
• Molecular Weight: 596.094
• Mol file: 214399-71-0.mol

Synonyms:

Chemical Property of [RuCp(PPh₃)(PPr(i)2Me)(Cl)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuCp(PPh₃)(PPr(i)2Me)(Cl)]

There total 1 articles about [RuCp(PPh₃)(PPr(i)2Me)(Cl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + diisopropylmethylphosphine (60054-88-8) → [RuCp(PPh3)(PPr(i)2Me)(Cl)] (214399-71-0)

Guidance literature:

In toluene; under Ar atm. P(i-Pr)2Me was added to soln. Ru complex in toluene and refluxed for 4 h; volatiles were removed in vacuo, residue was dissolved in toluene and passed through silica plug (ether), solvent was removed in vacuo;

DOI:10.1039/b806447d

Reference yield: 80.0%

pyridine-2-thione (2637-34-5,646031-56-3) + [RuCp(PPh3)(PPr(i)2Me)(Cl)] (214399-71-0) + sodium tetraphenyl borate (143-66-8) → (C5H5)Ru(P(C6H5)3)(P(CH(CH3)2)2CH3)(SC5H5N)(1+)*B(C6H5)4(1-)=[(C5H5)Ru(P(C6H5)3)(P(CH(CH3)2)2CH3)(SC5H5N)][B(C6H5)4] (214399-83-4)

Guidance literature:

In ethanol; N2 or Ar-atmosphere; stirring (15 min); filtering, washing (EtOH, petroleum ether), drying (vac.); elem. anal.;

DOI:10.1021/om980340h

Reference yield: 80.0%

[RuCp(PPh3)(PPr(i)2Me)(Cl)] (214399-71-0) + nitrogen (7727-37-9) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → C5H5Ru(PCH3(C3H7)2)P(C6H5)3N2(1+)*B((CF3)2C6H3)4(1-)=C5H5Ru(PCH3(C3H7)2)P(C6H5)3N2(B((CF3)2C6H3)4) (406187-97-1)

Guidance literature:

In fluorobenzene; byproducts: NaCl; to a soln. of complex in fluorobenzene under N2 was added solid Na-salt,N2 was injected through the mixt., stirred for 15 min at room temp.; filtered, the soln. was layered with petroleum ether, left to stand at room temp., crystals were dried under an Ar stream; elem. anal.;

DOI:10.1021/om010730v

upstream raw materials:

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

diisopropylmethylphosphine

Downstream raw materials:

(C₅H₅)Ru(P(C₆H₅)3)(P(CH(CH₃)2)2CH₃)(SC₅H₅N)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(C₅H₅)Ru(P(C₆H₅)3)(P(CH(CH₃)2)2CH₃)(SC₅H₅N)][B(C₆H₅)4]

C₅H₅Ru(PCH₃(C₃H₇)2)P(C₆H₅)3N₂⁽¹⁺⁾*B((CF₃)2C₆H₃)4^(1-)=C₅H₅Ru(PCH₃(C₃H₇)2)P(C₆H₅)3N₂(B((CF₃)2C₆H₃)4)

[CpRu(PMe(iPr)2)(η3-PPh3)][B(C6H3-(CF3)2-3,5)4]

[RuCp(PPh₃)(PPr(i)2Me)(H)]