silver(III)-5,10,15-tris(pentafluorophenyl)corrole

Base Information

• Chemical Name: silver(III)-5,10,15-tris(pentafluorophenyl)corrole
• CAS No.: 1191407-78-9
• Molecular Formula: C₃₇H₈AgF₁₅N₄
• Molecular Weight: 901.342
• Mol file: 1191407-78-9.mol

Synonyms:

Chemical Property of silver(III)-5,10,15-tris(pentafluorophenyl)corrole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of silver(III)-5,10,15-tris(pentafluorophenyl)corrole

There total 2 articles about silver(III)-5,10,15-tris(pentafluorophenyl)corrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

silver(I) acetate (563-63-3) + 5,10,15-tris(pentafluorophenyl)corrole → silver(III)-5,10,15-tris(pentafluorophenyl)corrole (1191407-78-9)

Guidance literature:

With pyridine; for 12h; Reflux;

DOI:10.1021/acs.orglett.6b02877

Reference yield: 36.0%

5,10,15-tris(pentafluorophenyl)corrole (238402-21-6) + silver(I) acetate (563-63-3) → silver(III)-5,10,15-tris(pentafluorophenyl)corrole (1191407-78-9)

Guidance literature:

In acetonitrile; Ag salt added to a soln. of ligand, stirred at room temp. for 18 h; filtered, evapd. (vac.), chromd. (silica gel, hexane, hexane/CHCl3), crystd. (acetone/H2O);

DOI:10.1021/ic900859a

Reference yield: 55.0%

N-iodo-succinimide (516-12-1) + silver(III)-5,10,15-tris(pentafluorophenyl)corrole (1191407-78-9) → silver(III)-2,17,18-triiodo-5,10,15-tris(pentafluorophenyl)corrole

Guidance literature:

With pyridine; for 12h; Inert atmosphere; Reflux;

DOI:10.1021/acs.orglett.6b02877

upstream raw materials:

5,10,15-tris(pentafluorophenyl)corrole

silver(I) acetate

Downstream raw materials:

[(TF₅PCor)Ag]^(1-)