[1'-(diphenylphosphinoyl)ferrocenyl]methanol

Base Information

Chemical Name:[1'-(diphenylphosphinoyl)ferrocenyl]methanol
CAS No.:1323155-77-6
Molecular Formula:C₂₃H₂₁FeO₂P
Molecular Weight:416.239
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [1'-(diphenylphosphinoyl)ferrocenyl]methanol

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Technology Process of [1'-(diphenylphosphinoyl)ferrocenyl]methanol

There total 1 articles about [1'-(diphenylphosphinoyl)ferrocenyl]methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 386702-89-2
1′-(diphenylphosphino)ferrocene-1-carbaldehyde

: 7722-84-1
dihydrogen peroxide

: 1323155-77-6
[1'-(diphenylphosphinoyl)ferrocenyl]methanol

Guidance literature:: In water; acetone; addn. of aq. H2O2 to soln. of Fe complex in acetone in air under stirring and cooling with ice, mixt. stirred for 30 min; diln. with brine, addn. of satd. Na2S2O3, evapn. under vac., extn. with ethyl acetate, org. extracts washed with brine, dried over MgSO4, filtration through silica gel with ethyl acetate, evapn. under vac., crystn. (ethyl acetate/hexane); elem. anal.;
DOI:10.1021/om2004805

Reference yield: 67.0%

: 1323155-77-6
[1'-(diphenylphosphinoyl)ferrocenyl]methanol

: 829-85-6
diphenylphosphane

: 1323155-84-5
1-(diphenylphosphinoyl)-1'-[(diphenylphosphino)methyl]ferrocene

Guidance literature:: With chlorotrimethylsilane; sodium iodide; In acetonitrile; byproducts: NaCl; under Ar, exclusion of direct daylight; addn. of Me3SiCl to soln. of Fe complex and NaI in MeCN, mixt. stirred for 5 min, addn. of Ph2PH, mixt. stirred overnight; diln. with brine and Et2O, org. phase sepd. and dried over MgSO4, Al2O3 added to filtrate, evapn., column chromy. (alumina, hexane/ethyl acetate1/1, then ethyl acetate), evapn. under vac., chromy. (silica gel, ethyl acetate), evapn.;
DOI:10.1021/om2004805