Benzoic acid (1R,2S)-1-[(1R,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methoxymethoxy-2-methyl-3-triethylsilanyloxy-propyl ester

Base Information

Chemical Name:Benzoic acid (1R,2S)-1-[(1R,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methoxymethoxy-2-methyl-3-triethylsilanyloxy-propyl ester
CAS No.:384817-55-4
Molecular Formula:C₄₇H₇₀O₆Si₂
Molecular Weight:787.24
Hs Code.:

Benzoic acid (1R,2S)-1-[(1R,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methoxymethoxy-2-methyl-3-triethylsilanyloxy-propyl ester

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Chemical Property of Benzoic acid (1R,2S)-1-[(1R,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methoxymethoxy-2-methyl-3-triethylsilanyloxy-propyl ester

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Technology Process of Benzoic acid (1R,2S)-1-[(1R,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methoxymethoxy-2-methyl-3-triethylsilanyloxy-propyl ester

There total 11 articles about Benzoic acid (1R,2S)-1-[(1R,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methoxymethoxy-2-methyl-3-triethylsilanyloxy-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 384817-55-4
Benzoic acid (1R,2S)-1-[(1R,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methoxymethoxy-2-methyl-3-triethylsilanyloxy-propyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 86 percent / imidazole / CH₂Cl₂ / 2 h / 20 °C

2: 99 percent / LiAlH₄ / diethyl ether / 0.5 h / 20 °C

3: 87 percent / TBHP; Ti(Oi-Pr)4; (+)-DET / 4 Angstroem MS / CH₂Cl₂ / 20 h / -20 °C

4: 66 percent / Ti(Oi-Pr)4 / CHCl₃ / 8 h / 20 °C

5: imidazole / CH₂Cl₂ / 0.03 h / 20 °C

6: DIPEA / CH₂Cl₂ / 8 h / 50 °C

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; lithium aluminium tetrahydride; diethyl (2R,3R)-tartrate; N-ethyl-N,N-diisopropylamine; 4 Angstroem MS; In diethyl ether; dichloromethane; chloroform; 3: Sharpless' asymmetric epoxidation;
DOI:10.1016/S0040-4039(01)01608-2

Reference yield:

: 380414-34-6
(E)-4-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-2-methyl-but-2-enoic acid

: 384817-55-4
Benzoic acid (1R,2S)-1-[(1R,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methoxymethoxy-2-methyl-3-triethylsilanyloxy-propyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 99 percent / aq. AcOH / tetrahydrofuran / 17 h / 20 °C

2: 93 percent / NaBH₄ / ethanol / 0.25 h / 20 °C

3: 86 percent / imidazole / CH₂Cl₂ / 2 h / 20 °C

4: 99 percent / LiAlH₄ / diethyl ether / 0.5 h / 20 °C

5: 87 percent / TBHP; Ti(Oi-Pr)4; (+)-DET / 4 Angstroem MS / CH₂Cl₂ / 20 h / -20 °C

6: 66 percent / Ti(Oi-Pr)4 / CHCl₃ / 8 h / 20 °C

7: imidazole / CH₂Cl₂ / 0.03 h / 20 °C

8: DIPEA / CH₂Cl₂ / 8 h / 50 °C

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium tetrahydroborate; lithium aluminium tetrahydride; diethyl (2R,3R)-tartrate; acetic acid; N-ethyl-N,N-diisopropylamine; 4 Angstroem MS; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; chloroform; 5: Sharpless' asymmetric epoxidation;
DOI:10.1016/S0040-4039(01)01608-2

Reference yield:

: 384817-69-0
(E)-4-((1R,5R,6R)-6-Formyl-5-isopropyl-2-methyl-cyclohex-2-enyl)-2-methyl-but-2-enoic acid ethyl ester

: 384817-55-4
Benzoic acid (1R,2S)-1-[(1R,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methoxymethoxy-2-methyl-3-triethylsilanyloxy-propyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 93 percent / NaBH₄ / ethanol / 0.25 h / 20 °C

2: 86 percent / imidazole / CH₂Cl₂ / 2 h / 20 °C

3: 99 percent / LiAlH₄ / diethyl ether / 0.5 h / 20 °C

4: 87 percent / TBHP; Ti(Oi-Pr)4; (+)-DET / 4 Angstroem MS / CH₂Cl₂ / 20 h / -20 °C

5: 66 percent / Ti(Oi-Pr)4 / CHCl₃ / 8 h / 20 °C

6: imidazole / CH₂Cl₂ / 0.03 h / 20 °C

7: DIPEA / CH₂Cl₂ / 8 h / 50 °C

With 1H-imidazole; titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium tetrahydroborate; lithium aluminium tetrahydride; diethyl (2R,3R)-tartrate; N-ethyl-N,N-diisopropylamine; 4 Angstroem MS; In diethyl ether; ethanol; dichloromethane; chloroform; 4: Sharpless' asymmetric epoxidation;
DOI:10.1016/S0040-4039(01)01608-2