Na{HRu3(CO)8(μ-PPh2)2}

Base Information

Chemical Name:Na{HRu3(CO)8(μ-PPh2)2}
CAS No.:126294-91-5
Molecular Formula:C₃₂H₂₁O₈P₂Ru₃*Na
Molecular Weight:921.661
Hs Code.:

Synonyms:

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Chemical Property of Na{HRu3(CO)8(μ-PPh2)2}

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Technology Process of Na{HRu3(CO)8(μ-PPh2)2}

There total 1 articles about Na{HRu3(CO)8(μ-PPh2)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 16940-66-2
sodium tetrahydroborate

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 829-85-6
diphenylphosphane

: 126294-91-5
Na{HRu3(CO)8(μ-PPh2)2}

Guidance literature:: In tetrahydrofuran; byproducts: carbon monoxide, hydrogen; (N2); dry solvents; dissolving Ru3(CO)12 and NaBH4 in THF, addn. of HPPh2, stirring at 20°C (6 h); removal of solvent;

Reference yield: 78.0%

: 126294-91-5
Na{HRu3(CO)8(μ-PPh2)2}

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 126294-88-0
{bis(triphenylphosphine)imminium}{HRu3(CO)8(μ-PPh2)2}

Guidance literature:: In methanol; (N2); dry solvents; dissolving Ru-compd. in MeOH, pptn. by addn. of (PPh3)2NCl; decantation, recrystn. (CH2Cl2/ether), drying in vac.; elem. anal.;

Reference yield: 42.0%

: 14694-95-2
Wilkinson's catalyst

: 126294-91-5
Na{HRu3(CO)8(μ-PPh2)2}

: 126294-89-1
{H2Ru3Rh(μ-CO)(CO)6(PPh3)2(μ-PPh2)(PPhC6H4)}

Guidance literature:: In dichloromethane; byproducts: sodium chloride, carbon monoxide, triphenylphosphine; (N2); dry solvents; addn. soln. of (PPh3)3RhCl in CH2Cl2 to fresh prepd. soln. of Ru-compd. dissolved in CH2Cl2, stirring at room temperature (5 h); removal of solvent, dissolving in CH2Cl2, TLC (SiO2, CH2Cl2/cyclohexane 2:3), extn. (CH2Cl2), recrystn. (CH2Cl2/pentane 1:2); elem. anal.;