Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl₂*(diethyl ether)

Base Information

• Chemical Name: Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl₂*(diethyl ether)
• CAS No.: 1050503-80-4
• Molecular Formula: C₄H₁₀O*C₂₀H₂₀Cl₂FeN₄O₄S₄
• Molecular Weight: 709.543
• Mol file: 1050503-80-4.mol

Synonyms:

Chemical Property of Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl₂*(diethyl ether)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl₂*(diethyl ether)

There total 2 articles about Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl₂*(diethyl ether) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

diethyl ether (60-29-7,927820-24-4) + 2-salicyloylhydrazono-1,3-dithiolane (266346-29-6) + iron(III) chloride (7705-08-0) → Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl2*(diethyl ether) (1050503-80-4)

Guidance literature:

In N,N-dimethyl-formamide; FeCl3 added to stirred soln. of ligand in DMF; stirred at room temp. overnight; crystd. in sealed tube by slow diffusion of Et2O for 2-3 d; elem. anal.;

DOI:10.1021/ic800522h

Reference yield:

diethyl ether (60-29-7,927820-24-4) + 2-salicyloylhydrazono-1,3-dithiolane (266346-29-6) + iron(II) chloride → Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl2*(diethyl ether) (1050503-80-4)

Guidance literature:

In N,N-dimethyl-formamide; FeCl2 reacted with ligand in DMF; crystd. by diffusion of Et2O;

DOI:10.1021/ic800522h

Reference yield:

Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl2*(diethyl ether) (1050503-80-4) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → Fe(2-salicyloylhydrazono-1,3-dithiolane(-1H))2(DMF)Cl

Guidance literature:

With air; In N,N-dimethyl-formamide; DMF soln. of Fe complex stirred under air; not isolated;

DOI:10.1021/ic800522h

upstream raw materials:

diethyl ether

2-salicyloylhydrazono-1,3-dithiolane

iron(III) chloride