tert-butylammonium diphenylthiophosphinoylglycolate

Base Information

• Chemical Name: tert-butylammonium diphenylthiophosphinoylglycolate
• CAS No.: 1384754-34-0
• Molecular Formula: C₄H₁₁N*C₁₄H₁₃O₃PS
• Molecular Weight: 365.433
• Mol file: 1384754-34-0.mol

Synonyms:

Chemical Property of tert-butylammonium diphenylthiophosphinoylglycolate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butylammonium diphenylthiophosphinoylglycolate

There total 5 articles about tert-butylammonium diphenylthiophosphinoylglycolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

tert-butylamine (75-64-9) + diphenylphosphane (829-85-6) + 2,2-dihydroxyacetic acid (563-96-2) → tert-butylammonium diphenylthiophosphinoylglycolate (1384754-34-0)

Guidance literature:

tert-butylamine; diphenylphosphane; 2,2-dihydroxyacetic acid; In diethyl ether; Inert atmosphere;

With sulfur; for 24h; Reflux; Inert atmosphere;

DOI:10.1016/j.poly.2012.04.019

Reference yield:

chloro-diphenylphosphine (1079-66-9,74391-44-9) → tert-butylammonium diphenylthiophosphinoylglycolate (1384754-34-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: water; sodium carbonate / diethyl ether

2.1: lithium aluminium tetrahydride / diethyl ether

3.1: diethyl ether / Inert atmosphere

3.2: 24 h / Reflux; Inert atmosphere

With lithium aluminium tetrahydride; water; sodium carbonate; In diethyl ether;

DOI:10.1016/j.poly.2012.04.019

Reference yield:

tert-butylamino(diphenylphosphanyl)acetic acid (843664-57-3) → tert-butylammonium diphenylthiophosphinoylglycolate (1384754-34-0)

Guidance literature:

Multi-step reaction with 2 steps

1: sulfur / tetrahydrofuran / 15 h / 20 °C / Inert atmosphere; Schlenk technique

2: water-d2 / d⁽⁴⁾-methanol

With water-d2; sulfur; In tetrahydrofuran; d⁽⁴⁾-methanol;

DOI:10.1016/j.tet.2015.05.101

upstream raw materials:

chloro-diphenylphosphine

tert-butylamine

diphenylphosphane

2,2-dihydroxyacetic acid