CID 6377989

Base Information

Chemical Name:CID 6377989
CAS No.:75602-13-0
Molecular Formula:C₁₂H₈ClMnO₅Sn
Molecular Weight:441.294
Hs Code.:
NSC Number:319699

Synonyms:NSC319699;75602-13-0;NSC-319699

Suppliers and Price of CID 6377989

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of CID 6377989

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:1
Exact Mass:441.84627
Heavy Atom Count:20
Complexity:247

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C[Sn](C1=CC=CC=C1)Cl.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Mn]

Technology Process of CID 6377989

There total 1 articles about CID 6377989 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 10170-69-1
dimanganese decacarbonyl

: 15649-26-0
methylphenyltin(IV) dichloride

: 75602-13-0
(C₆H₅)CH₃ClSnMn(CO)5

Guidance literature:: With NaHg(x); In tetrahydrofuran; (N2), (Mn(CO)5)2 and NaHg(x) in THF filtered, added to soln. of PhMeSnCl2 in THF (2h); evapd., extracted with Et2O, washed with water, dried over MgSO4, filtered, evapd., recrystd. from petroleum ether at 40°C, elem. anal.;

Reference yield:

: 75602-13-0
(C₆H₅)CH₃ClSnMn(CO)5

: 824-47-5
(1-chloropropan-2-yl)benzene

: 75602-18-5
(C₆H₅)CH₃Sn(Mn(CO)5)2

: methylphenylbis(2-phenylpropyl)tin

Guidance literature:: With magnesium; In diethyl ether; to Mg and PhMeCHCH2Cl in Et2O added dropwise soln. of PhMeClSnMn(CO)5 in Et2O, mixture refluxed for 1 h; hydrolyzed with H2O, dried on MgSO4, evapd., crystd. in refrigerator, chromd. (SiO2, C6H6/petroleum ether 1/5);

Reference yield:

: 75602-13-0
(C₆H₅)CH₃ClSnMn(CO)5

: 90-11-9
1-Bromonaphthalene

: 79895-13-9
SnC₁₀H₇CH₃C₆H₅Mn(CO)5

Guidance literature:: With magnesium; In diethyl ether; byproducts: PhMeSn[Mn(CO)5]2, PhMeNp2Sn; Grignard reagent prepared from 1-naphthyl bromide and Mg in Et2O, this added to Sn-Mn compd. at 0°C, reaction completed after 3 h at room temp.; hydrolysis, naphthalene sublimed, product mixt. purified by chromy.;
DOI:10.1016/S0022-328X(00)85782-4